Reactions between boron and magnesium halides and the bicyclic guanidine hppH (1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidine): guanidinates with new structural motifs
Herein we report on the synthesis and chemical properties of some binuclear and oligonuclear compounds of boron- and magnesium-containing bridging guanidinate ligands. These species were prepared by reaction of the bicyclic guanidine hppH (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine) a...
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| Hauptverfasser: | , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
16 March 2010
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| In: |
Zeitschrift für anorganische und allgemeine Chemie
Year: 2010, Jahrgang: 636, Heft: 3-4, Pages: 543-550 |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.200900358 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/zaac.200900358 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.200900358 |
| Verfasserangaben: | Oxana Ciobanu, Alexander Fuchs, Matthias Reinmuth, Anna Lebkücher, Elisabeth Kaifer, Hubert Wadepohl, and Hans-Jörg Himmel |
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| 520 | |a Herein we report on the synthesis and chemical properties of some binuclear and oligonuclear compounds of boron- and magnesium-containing bridging guanidinate ligands. These species were prepared by reaction of the bicyclic guanidine hppH (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine) and BCl3, the diborane(4) B2Cl2(NMe2)2 or the Grignard compound MeMgBr. The experimental results are complemented by quantum chemical (DFT) calculations. | ||
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| 650 | 4 | |a Oligonuclear complexes | |
| 650 | 4 | |a Reaction mechanisms | |
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