Gold-catalyzed synthesis of N,O-heterocycles

The selective synthesis of oxazoles, alkylidene oxazoles, and 1,3-oxazines from N -propargyl carboxamides by choosing gold(III) or gold(I) catalysts and selecting terminal or internal alkynes as substrates is discussed. The mechanistic studies based on labeling experiments and intensive in situ NMR...

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Main Author: Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:German
Published: 18. Februar 2010
In: Pure and applied chemistry
Year: 2010, Volume: 82, Issue: 3, Pages: 657-668
ISSN:1365-3075
DOI:10.1351/PAC-CON-09-10-17
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1351/PAC-CON-09-10-17
Verlag, lizenzpflichtig, Volltext: https://www.degruyterbrill.com/document/doi/10.1351/PAC-CON-09-10-17/html
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Author Notes:A. Stephen K. Hashmi (Institute of Organic Chemistry, Ruprecht-Karls-University Heidelberg)
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Gold-catalyzed synthesis of N,O-heterocycles by Hashmi, A. Stephen K. (Author)


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Article (Journal)