Triazolate counter ions in au' complexes: catalysts with improved thermal stability
Counter revolution: Most homogeneous gold-catalyzed transformations employ gold(I) complexes with weakly coordinating anions, which, their remarkable activity notwithstanding, lack stability at higher temperatures. Shi et al. have described the synthesis of simple phosphine-based gold(I) complexes w...
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| Main Authors: | , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
[February 8, 2010]
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| In: |
ChemCatChem
Year: 2010, Volume: 2, Issue: 2, Pages: 133-134 |
| ISSN: | 1867-3899 |
| DOI: | 10.1002/cctc.200900280 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/cctc.200900280 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/cctc.200900280 
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| Author Notes: | A. Stephen K. Hashmi and Christian Lothschütz |
MARC
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| 520 | |a Counter revolution: Most homogeneous gold-catalyzed transformations employ gold(I) complexes with weakly coordinating anions, which, their remarkable activity notwithstanding, lack stability at higher temperatures. Shi et al. have described the synthesis of simple phosphine-based gold(I) complexes with triazolates as counter ions. The compounds are highly thermostable and good catalysts for intermolecular hydroaminations. | ||
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