Gold catalysis: in situ EXAFS study of homogeneous oxidative esterification

Gold complexes were prepared and investigated as catalysts for the oxidative esterification of aldehydes. Stabilisation by pyridine ligands gave good conversions and the in situ extended X-ray absorption fine structure (EXAFS) study of the reactions indicated that the reaction mixtures contained onl...

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Main Authors: Hashmi, A. Stephen K. (Author) , Lothschütz, Christian (Author) , Ackermann, Martin (Author) , Döpp, René (Author) , Anantharaman, Sankaran (Author) , Marchetti, Benjamin (Author) , Bertagnolli, Helmut (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: [July 19, 2010]
In: Chemistry - a European journal
Year: 2010, Volume: 16, Issue: 27, Pages: 8012-8019
ISSN:1521-3765
DOI:10.1002/chem.200903450
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.200903450
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.200903450
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Author Notes:A. Stephen K. Hashmi, Christian Lothschütz, Martin Ackermann, René Doepp, Sankaran Anantharaman, Benjamin Marchetti, Helmut Bertagnolli, and Frank Rominger

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520 |a Gold complexes were prepared and investigated as catalysts for the oxidative esterification of aldehydes. Stabilisation by pyridine ligands gave good conversions and the in situ extended X-ray absorption fine structure (EXAFS) study of the reactions indicated that the reaction mixtures contained only mononuclear gold species. Thus, this is the first proof for a homogeneous gold-catalysed oxidation reaction; the presence of nanoparticles could be excluded experimentally. 
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