Carbenes made easy: formation of unsymmetrically substituted N-heterocyclic carbene complexes of palladium(II), platinum(II) and gold(I) from coordinated isonitriles and their catalytic activity

From palladium(II) or platinum(II) bis(isonitrile) complexes and from gold(I) isonitrile complexes, both easily available from simple precursors, the corresponding mono-N-heterocyclic carbene (NHC) complexes could be obtained selectively in good yields under very mild conditions. The reagents are si...

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Main Authors: Hashmi, A. Stephen K. (Author) , Lothschütz, Christian (Author) , Böhling, Constantin (Author) , Hengst, Tobias (Author) , Hubbert, Christoph (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: [November 22, 2010]
In: Advanced synthesis & catalysis
Year: 2010, Volume: 352, Issue: 17, Pages: 3001-3012
ISSN:1615-4169
DOI:10.1002/adsc.201000472
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201000472
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201000472
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Author Notes:A. Stephen K. Hashmi, Christian Lothschütz, Constantin Böhling, Tobias Hengst, Christoph Hubbert, and Frank Rominger