Carbenes made easy: formation of unsymmetrically substituted N-heterocyclic carbene complexes of palladium(II), platinum(II) and gold(I) from coordinated isonitriles and their catalytic activity
From palladium(II) or platinum(II) bis(isonitrile) complexes and from gold(I) isonitrile complexes, both easily available from simple precursors, the corresponding mono-N-heterocyclic carbene (NHC) complexes could be obtained selectively in good yields under very mild conditions. The reagents are si...
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| Main Authors: | , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
[November 22, 2010]
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| In: |
Advanced synthesis & catalysis
Year: 2010, Volume: 352, Issue: 17, Pages: 3001-3012 |
| ISSN: | 1615-4169 |
| DOI: | 10.1002/adsc.201000472 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201000472 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201000472 |
| Author Notes: | A. Stephen K. Hashmi, Christian Lothschütz, Constantin Böhling, Tobias Hengst, Christoph Hubbert, and Frank Rominger |