On the trapping of vinylgold intermediates
An internal aryl-substituted ortho-alkynylphenol and a similar aniline with stoichiometric amounts of N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene-gold tosylate [(IPr)AuOTs] and triethylamine gave the aurated heterocycles as stable intermediates of the corresponding gold(I)-catalysed hydrooxyla...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
[April 19, 2010]
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| In: |
Advanced synthesis & catalysis
Year: 2010, Volume: 352, Issue: 6, Pages: 971-975 |
| ISSN: | 1615-4169 |
| DOI: | 10.1002/adsc.201000011 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201000011 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201000011 
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| Author Notes: | A. Stephen K. Hashmi, Tanuja Dondeti Ramamurthi, and Frank Rominger |
| Summary: | An internal aryl-substituted ortho-alkynylphenol and a similar aniline with stoichiometric amounts of N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene-gold tosylate [(IPr)AuOTs] and triethylamine gave the aurated heterocycles as stable intermediates of the corresponding gold(I)-catalysed hydrooxylation and hydroamination reactions. X-ray crystal structure analyses of both products could be obtained. A similar internal alkyl-substituted ortho-alkynylphenol gave only the cycloisomerised product, no aurated intermediate could be detected. |
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| Item Description: | First published: 15 April 2010 Gesehen am 27.03.2023 |
| Physical Description: | Online Resource |
| ISSN: | 1615-4169 |
| DOI: | 10.1002/adsc.201000011 |