The dioxygen complexes of VO2

By matrix isolation in solid Ne and Kr, VO, VO2, and the complexes VO2(O2) with one superoxo ligand and VO2(O2)2 with one superoxo and one neutral dioxygen ligand, as well as V2O2 and V2O4 have been generated. For VO2(O2), transitions of five vibrational modes have been observed, and for VO2(O2)2, t...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Hübner, Olaf (VerfasserIn) , Himmel, Hans-Jörg (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2021
In: Zeitschrift für anorganische und allgemeine Chemie
Year: 2021, Jahrgang: 647, Heft: 18, Pages: 1764-1777
ISSN:1521-3749
DOI:10.1002/zaac.202100156
Online-Zugang:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/zaac.202100156
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.202100156
Volltext
Verfasserangaben:Olaf Hübner and Hans-Jörg Himmel

MARC

LEADER 00000caa a2200000 c 4500
001 1840461098
003 DE-627
005 20230707005832.0
007 cr uuu---uuuuu
008 230329s2021 xx |||||o 00| ||eng c
024 7 |a 10.1002/zaac.202100156  |2 doi 
035 |a (DE-627)1840461098 
035 |a (DE-599)KXP1840461098 
035 |a (OCoLC)1389537965 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Hübner, Olaf  |e VerfasserIn  |0 (DE-588)1020547707  |0 (DE-627)691256500  |0 (DE-576)360702864  |4 aut 
245 1 4 |a The dioxygen complexes of VO2  |c Olaf Hübner and Hans-Jörg Himmel 
246 3 0 |a two 
246 3 3 |a The dioxygen complexes of VO 2 
264 1 |c 2021 
300 |a 14 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Im Titel ist "2" bei "VO" tiefgestellt 
500 |a Gesehen am 29.03.2023 
520 |a By matrix isolation in solid Ne and Kr, VO, VO2, and the complexes VO2(O2) with one superoxo ligand and VO2(O2)2 with one superoxo and one neutral dioxygen ligand, as well as V2O2 and V2O4 have been generated. For VO2(O2), transitions of five vibrational modes have been observed, and for VO2(O2)2, transitions belonging to seven vibrational modes, confirming and extending former Ar matrix results. Attempts to stabilise the cyclic V(O2) peroxide by use of the heavier Kr matrix were not successful. By accompanying MRCI calculations on VO2 and V(O2), vibrational frequencies have been determined. Furthermore, the investigation is assisted by density functional calculations with the TPSS functional. Possibly, also one vibrational transition of the VO3 molecule has been observed. 
650 4 |a dioxygen complexes 
650 4 |a infrared spectroscopy 
650 4 |a matrix isolation 
650 4 |a oxidation 
650 4 |a vanadium 
700 1 |a Himmel, Hans-Jörg  |d 1970-  |e VerfasserIn  |0 (DE-588)120090368  |0 (DE-627)080439683  |0 (DE-576)292036159  |4 aut 
773 0 8 |i Enthalten in  |t Zeitschrift für anorganische und allgemeine Chemie  |d Weinheim : Wiley-VCH, 1892  |g 647(2021), 18, Seite 1764-1777  |h Online-Ressource  |w (DE-627)271601191  |w (DE-600)1481139-X  |w (DE-576)078709245  |x 1521-3749  |7 nnas  |a The dioxygen complexes of VO2 
773 1 8 |g volume:647  |g year:2021  |g number:18  |g pages:1764-1777  |g extent:14  |a The dioxygen complexes of VO2 
856 4 0 |u https://doi.org/10.1002/zaac.202100156  |x Verlag  |x Resolving-System  |z kostenfrei  |3 Volltext 
856 4 0 |u https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.202100156  |x Verlag  |z kostenfrei  |3 Volltext 
951 |a AR 
992 |a 20230329 
993 |a Article 
994 |a 2021 
998 |g 120090368  |a Himmel, Hans-Jörg  |m 120090368:Himmel, Hans-Jörg  |d 120000  |d 120200  |e 120000PH120090368  |e 120200PH120090368  |k 0/120000/  |k 1/120000/120200/  |p 2  |y j 
998 |g 1020547707  |a Hübner, Olaf  |m 1020547707:Hübner, Olaf  |d 500000  |d 501249  |e 500000PH1020547707  |e 501249PH1020547707  |k 0/500000/  |k 1/500000/501249/  |p 1  |x j 
999 |a KXP-PPN1840461098  |e 4299581547 
BIB |a Y 
SER |a journal 
JSO |a {"language":["eng"],"titleAlt":[{"title":"The dioxygen complexes of VO 2"}],"person":[{"given":"Olaf","role":"aut","family":"Hübner","display":"Hübner, Olaf"},{"given":"Hans-Jörg","role":"aut","display":"Himmel, Hans-Jörg","family":"Himmel"}],"name":{"displayForm":["Olaf Hübner and Hans-Jörg Himmel"]},"physDesc":[{"extent":"14 S."}],"relHost":[{"language":["ger"],"part":{"volume":"647","extent":"14","text":"647(2021), 18, Seite 1764-1777","issue":"18","year":"2021","pages":"1764-1777"},"titleAlt":[{"title":"ZAAC"}],"recId":"271601191","physDesc":[{"extent":"Online-Ressource"}],"id":{"doi":["10.1002/(ISSN)1521-3749"],"zdb":["1481139-X"],"issn":["1521-3749"],"eki":["271601191"]},"title":[{"title":"Zeitschrift für anorganische und allgemeine Chemie","subtitle":"ZAAC = Journal of inorganic and general chemistry","title_sort":"Zeitschrift für anorganische und allgemeine Chemie"}],"origin":[{"dateIssuedDisp":"1892-","dateIssuedKey":"1892","publisher":"Wiley-VCH","publisherPlace":"Weinheim"}],"pubHistory":["1.1892 -"],"note":["Gesehen am 28.02.2005"],"type":{"bibl":"periodical","media":"Online-Ressource"},"disp":"The dioxygen complexes of VO2Zeitschrift für anorganische und allgemeine Chemie","titleTranslated":[{"translated":"Journal of inorganic and general chemistry"}]}],"recId":"1840461098","id":{"eki":["1840461098"],"doi":["10.1002/zaac.202100156"]},"note":["Im Titel ist \"2\" bei \"VO\" tiefgestellt","Gesehen am 29.03.2023"],"origin":[{"dateIssuedKey":"2021","dateIssuedDisp":"2021"}],"title":[{"title_sort":"dioxygen complexes of VO2","title":"The dioxygen complexes of VO2"}],"type":{"bibl":"article-journal","media":"Online-Ressource"}} 
SRT |a HUEBNEROLADIOXYGENCO2021