Stimulation of redox-induced electron transfer by interligand hydrogen bonding in a cobalt complex with redox-active guanidine ligand
Octahedrally coordinated cobalt(II) complexes with a redox-active bisguanidine ligand and acac co-ligands were synthesized and their redox chemistry analysed in detail. The N−H functions in a bisguanidine ligand with partially alkylated guanidino groups form N−H⋅⋅⋅O hydrogen bonds with the acac co-l...
Gespeichert in:
| Hauptverfasser: | , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2021
|
| In: |
Angewandte Chemie. International edition
Year: 2021, Jahrgang: 60, Heft: 18, Pages: 10415-10422 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.202101423 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/anie.202101423 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202101423 
|
| Verfasserangaben: | Lukas Lohmeyer, Florian Schön, Elisabeth Kaifer, and Hans-Jörg Himmel |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1842949012 | ||
| 003 | DE-627 | ||
| 005 | 20230707005507.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 230417s2021 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/anie.202101423 |2 doi | |
| 035 | |a (DE-627)1842949012 | ||
| 035 | |a (DE-599)KXP1842949012 | ||
| 035 | |a (OCoLC)1389537829 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Lohmeyer, Lukas |d 1993- |e VerfasserIn |0 (DE-588)1246462664 |0 (DE-627)1779068328 |4 aut | |
| 245 | 1 | 0 | |a Stimulation of redox-induced electron transfer by interligand hydrogen bonding in a cobalt complex with redox-active guanidine ligand |c Lukas Lohmeyer, Florian Schön, Elisabeth Kaifer, and Hans-Jörg Himmel |
| 264 | 1 | |c 2021 | |
| 300 | |a 8 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 17.04.2023 | ||
| 520 | |a Octahedrally coordinated cobalt(II) complexes with a redox-active bisguanidine ligand and acac co-ligands were synthesized and their redox chemistry analysed in detail. The N−H functions in a bisguanidine ligand with partially alkylated guanidino groups form N−H⋅⋅⋅O hydrogen bonds with the acac co-ligands, thereby massively influencing the redox chemistry. For all complexes, the first one-electron oxidation is metal-centred, leading to CoIII complexes with neutral bisguanidine ligand units. Further one-electron oxidation is ligand-centred in the case of Co-bisguanidine complexes with fully alkylated guanidino groups, giving CoIII complexes with radical monocationic bisguanidine ligands. On the other hand, the hydrogen-bond strengthening upon oxidation of the Co-bisguanidine complex with partially alkylated guanidino groups initiates metal reduction (CoIII→CoII) and two-electron oxidation of the guanidine ligand, providing the first example for the stimulation of redox-induced electron transfer by interligand hydrogen bonding. | ||
| 650 | 4 | |a cobalt | |
| 650 | 4 | |a electron transfer | |
| 650 | 4 | |a guanidine | |
| 650 | 4 | |a hydrogen bonding | |
| 650 | 4 | |a redox active ligand | |
| 700 | 1 | |a Schön, Florian |e VerfasserIn |0 (DE-588)1160896038 |0 (DE-627)1024289516 |0 (DE-576)50622578X |4 aut | |
| 700 | 1 | |a Kaifer, Elisabeth |e VerfasserIn |0 (DE-588)1020547898 |0 (DE-627)691256624 |0 (DE-576)166913820 |4 aut | |
| 700 | 1 | |a Himmel, Hans-Jörg |d 1970- |e VerfasserIn |0 (DE-588)120090368 |0 (DE-627)080439683 |0 (DE-576)292036159 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Angewandte Chemie. International edition |d Weinheim : Wiley-VCH, 1998 |g 60(2021), 18, Seite 10415-10422 |h Online-Ressource |w (DE-627)320497879 |w (DE-600)2011836-3 |w (DE-576)111552060 |x 1521-3773 |7 nnas |a Stimulation of redox-induced electron transfer by interligand hydrogen bonding in a cobalt complex with redox-active guanidine ligand |
| 773 | 1 | 8 | |g volume:60 |g year:2021 |g number:18 |g pages:10415-10422 |g extent:8 |a Stimulation of redox-induced electron transfer by interligand hydrogen bonding in a cobalt complex with redox-active guanidine ligand |
| 775 | 0 | 8 | |i Parallele Sprachausgabe |n deutsch |a Lohmeyer, Lukas, 1993 - |t Stimulierung eines redoxinduzierten Elektronentransfers durch Interligand-Wasserstoffbrücken in einem Cobaltkomplex mit redoxaktivem Guanidin-Liganden |d 2021 |w (DE-627)1842949756 |
| 856 | 4 | 0 | |u https://doi.org/10.1002/anie.202101423 |x Verlag |x Resolving-System |z kostenfrei |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202101423 |x Verlag |z kostenfrei |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20230417 | ||
| 993 | |a Article | ||
| 994 | |a 2021 | ||
| 998 | |g 120090368 |a Himmel, Hans-Jörg |m 120090368:Himmel, Hans-Jörg |d 120000 |d 120200 |e 120000PH120090368 |e 120200PH120090368 |k 0/120000/ |k 1/120000/120200/ |p 4 |y j | ||
| 998 | |g 1020547898 |a Kaifer, Elisabeth |m 1020547898:Kaifer, Elisabeth |d 120000 |d 120200 |e 120000PK1020547898 |e 120200PK1020547898 |k 0/120000/ |k 1/120000/120200/ |p 3 | ||
| 998 | |g 1246462664 |a Lohmeyer, Lukas |m 1246462664:Lohmeyer, Lukas |d 120000 |d 120200 |e 120000PL1246462664 |e 120200PL1246462664 |k 0/120000/ |k 1/120000/120200/ |p 1 |x j | ||
| 999 | |a KXP-PPN1842949012 |e 4309607705 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"language":["eng"],"person":[{"family":"Lohmeyer","display":"Lohmeyer, Lukas","given":"Lukas","role":"aut"},{"display":"Schön, Florian","family":"Schön","given":"Florian","role":"aut"},{"display":"Kaifer, Elisabeth","family":"Kaifer","given":"Elisabeth","role":"aut"},{"role":"aut","given":"Hans-Jörg","family":"Himmel","display":"Himmel, Hans-Jörg"}],"relHost":[{"id":{"doi":["10.1002/(ISSN)1521-3773"],"zdb":["2011836-3"],"issn":["1521-3773"],"eki":["320497879"]},"recId":"320497879","physDesc":[{"extent":"Online-Ressource"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"disp":"Stimulation of redox-induced electron transfer by interligand hydrogen bonding in a cobalt complex with redox-active guanidine ligandAngewandte Chemie. International edition","title":[{"title":"Angewandte Chemie","title_sort":"Angewandte Chemie","subtitle":"a journal of the Gesellschaft Deutscher Chemiker","partname":"International edition"}],"pubHistory":["37.1998 -"],"origin":[{"dateIssuedDisp":"1998-","dateIssuedKey":"1998","publisher":"Wiley-VCH","publisherPlace":"Weinheim"}],"note":["Gesehen am 20.12.2022","Fortsetzung der Druck-Ausgabe"],"part":{"year":"2021","pages":"10415-10422","text":"60(2021), 18, Seite 10415-10422","issue":"18","volume":"60","extent":"8"},"titleAlt":[{"title":"Angewandte Chemie / International edition"}],"language":["eng"],"corporate":[{"role":"isb","display":"Gesellschaft Deutscher Chemiker"}]}],"recId":"1842949012","name":{"displayForm":["Lukas Lohmeyer, Florian Schön, Elisabeth Kaifer, and Hans-Jörg Himmel"]},"physDesc":[{"extent":"8 S."}],"id":{"eki":["1842949012"],"doi":["10.1002/anie.202101423"]},"origin":[{"dateIssuedDisp":"2021","dateIssuedKey":"2021"}],"note":["Gesehen am 17.04.2023"],"title":[{"title_sort":"Stimulation of redox-induced electron transfer by interligand hydrogen bonding in a cobalt complex with redox-active guanidine ligand","title":"Stimulation of redox-induced electron transfer by interligand hydrogen bonding in a cobalt complex with redox-active guanidine ligand"}],"type":{"bibl":"article-journal","media":"Online-Ressource"}} | ||
| SRT | |a LOHMEYERLUSTIMULATIO2021 | ||