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New low-temperature NMR studies establish the presence of a second equatorial: apical isomer of [(R,S)-Binaphos](CO)2RhH

The important enantioselective hydroformylation catalyst [(R,S)-Binaphos](CO)2RhH has been reexamained by low-temperature NMR spectroscopy. Both 1H and 31P NMR spectroscopy at −90 °C allow direct observation of a mixture of two apical−equatorial chelates. The major chelate, 1eq,ap, was shown to have...

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Hauptverfasser: Castillo Molina, Dante Alberto (VerfasserIn) , Casey, Charles P. (VerfasserIn) , Müller, Imke (VerfasserIn) , Nozaki, Kyoko (VerfasserIn) , Jäkel, Christoph (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 6 July 2010
In: Organometallics
Year: 2010, Jahrgang: 29, Heft: 15, Pages: 3362-3367
ISSN:1520-6041
DOI:10.1021/om100323q
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om100323q
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Verfasserangaben:Dante A. Castillo Molina, Charles P. Casey, Imke Müller, Kyoko Nozaki, and Christoph Jäkel

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