Electron-transfer properties of an efficient nonheme iron oxidation catalyst with a tetradentate bispidine ligand
The oxidation catalyst [(L)FeIVO] (see picture; L is a tetradentate bispidine ligand) has the highest known one-electron reduction potential for a FeIVO species (0.73 V vs. SCE). Investigations into the electron-transfer kinetics show a linear correlation with the bond dissociation energy of the o...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
March 12, 2010
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| In: |
Angewandte Chemie. International edition
Year: 2010, Jahrgang: 49, Heft: 14, Pages: 2622-2625 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200904427 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200904427 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200904427 |
| Verfasserangaben: | Peter Comba, Shunichi Fukuzumi, Hiroaki Kotani, and Steffen Wunderlich |
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| 520 | |a The oxidation catalyst [(L)FeIVO] (see picture; L is a tetradentate bispidine ligand) has the highest known one-electron reduction potential for a FeIVO species (0.73 V vs. SCE). Investigations into the electron-transfer kinetics show a linear correlation with the bond dissociation energy of the organic substrates. | ||
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