Structural stability of a golden semiconducting orthorhombic polymorph of Ti2O3 under high pressures and high temperatures
An orthorhombic polymorph of titanium oxide (Ti2O3) has been synthesized at high pressure-high temperature (HP-HT) conditions. It has been refined in the Pnma space group and the Th2S3 structural type with the unit cell parameters as follows: a = 7.8248(6) Å, b = 2.8507(4) Å, c = 8.0967(3) Å, V =...
Gespeichert in:
| Hauptverfasser: | , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
31 August 2010
|
| In: |
Journal of physics. Condensed matter
Year: 2010, Jahrgang: 22, Heft: 37, Pages: 1-10 |
| ISSN: | 1361-648X |
| DOI: | 10.1088/0953-8984/22/37/375402 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1088/0953-8984/22/37/375402 Verlag, lizenzpflichtig, Volltext: https://dx.doi.org/10.1088/0953-8984/22/37/375402 
|
| Verfasserangaben: | Sergey V. Ovsyannikov, Xiang Wu, Vladimir V. Shchennikov, Alexander E. Karkin, Natalia Dubrovinskaia, Gaston Garbarino amd Leonid Dubrovinsky |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 185071357X | ||
| 003 | DE-627 | ||
| 005 | 20230710130026.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 230621s2010 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1088/0953-8984/22/37/375402 |2 doi | |
| 035 | |a (DE-627)185071357X | ||
| 035 | |a (DE-599)KXP185071357X | ||
| 035 | |a (OCoLC)1389793774 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 29 |2 sdnb | ||
| 100 | 1 | |a Ovsyannikov, Sergey |e VerfasserIn |0 (DE-588)1163817198 |0 (DE-627)1028142811 |0 (DE-576)508224780 |4 aut | |
| 245 | 1 | 0 | |a Structural stability of a golden semiconducting orthorhombic polymorph of Ti2O3 under high pressures and high temperatures |c Sergey V. Ovsyannikov, Xiang Wu, Vladimir V. Shchennikov, Alexander E. Karkin, Natalia Dubrovinskaia, Gaston Garbarino amd Leonid Dubrovinsky |
| 246 | 3 | 3 | |a Structural stability of a golden semiconducting orthorhombic polymorph of Ti 2 O 3 under high pressures and high temperatures |
| 264 | 1 | |c 31 August 2010 | |
| 300 | |a 10 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Im Text sind "2" und "3" tiefgestellt | ||
| 500 | |a Gesehen am 21.06.2023 | ||
| 520 | |a An orthorhombic polymorph of titanium oxide (Ti2O3) has been synthesized at high pressure-high temperature (HP-HT) conditions. It has been refined in the Pnma space group and the Th2S3 structural type with the unit cell parameters as follows: a = 7.8248(6) Å, b = 2.8507(4) Å, c = 8.0967(3) Å, V = 180.61(1) Å3 and Z = 4. The samples of Pnma-Ti2O3 were of a golden colour, in contrast to the conventional black corundum-structured Ti2O3. The structural stability of this polymorph has been examined by simultaneous Raman and x-ray diffraction studies under high pressure over 70 GPa and high temperature over 2200 K. No phase transformations or chemical reactions have been established. The electrical resistivity of Th2S3-structured Ti2O3 samples showed a semiconducting behaviour and, at ambient conditions, was equal to 0.20-0.46 Ω cm. Conventional near-infrared absorption spectroscopy established the absence of energy gaps above 0.25 eV. | ||
| 700 | 1 | |a Wu, Xiang |e VerfasserIn |4 aut | |
| 700 | 1 | |a Shchennikov, Vladimir V. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Karkin, Alexander E. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Dubrovinskaia, Natalia |d 1961- |e VerfasserIn |0 (DE-588)1163579734 |0 (DE-627)102790260X |0 (DE-576)508070732 |4 aut | |
| 700 | 1 | |a Garbarino, Gaston |e VerfasserIn |4 aut | |
| 700 | 1 | |a Dubrovinsky, Leonid |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Journal of physics. Condensed matter |d Bristol : IOP Publ., 1989 |g 22(2010), 37, Artikel-ID 375402, Seite 1-10 |h Online-Ressource |w (DE-627)268759936 |w (DE-600)1472968-4 |w (DE-576)07761013X |x 1361-648X |7 nnas |a Structural stability of a golden semiconducting orthorhombic polymorph of Ti2O3 under high pressures and high temperatures |
| 773 | 1 | 8 | |g volume:22 |g year:2010 |g number:37 |g elocationid:375402 |g pages:1-10 |g extent:10 |a Structural stability of a golden semiconducting orthorhombic polymorph of Ti2O3 under high pressures and high temperatures |
| 856 | 4 | 0 | |u https://doi.org/10.1088/0953-8984/22/37/375402 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://dx.doi.org/10.1088/0953-8984/22/37/375402 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20230621 | ||
| 993 | |a Article | ||
| 994 | |a 2010 | ||
| 998 | |g 1163579734 |a Dubrovinskaia, Natalia |m 1163579734:Dubrovinskaia, Natalia |d 120000 |d 121000 |e 120000PD1163579734 |e 121000PD1163579734 |k 0/120000/ |k 1/120000/121000/ |p 5 | ||
| 999 | |a KXP-PPN185071357X |e 4341174924 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"id":{"doi":["10.1088/0953-8984/22/37/375402"],"eki":["185071357X"]},"origin":[{"dateIssuedKey":"2010","dateIssuedDisp":"31 August 2010"}],"name":{"displayForm":["Sergey V. Ovsyannikov, Xiang Wu, Vladimir V. Shchennikov, Alexander E. Karkin, Natalia Dubrovinskaia, Gaston Garbarino amd Leonid Dubrovinsky"]},"relHost":[{"id":{"issn":["1361-648X"],"eki":["268759936"],"doi":["10.1088/issn.0953-8984"],"zdb":["1472968-4"]},"origin":[{"publisherPlace":"Bristol","publisher":"IOP Publ.","dateIssuedKey":"1989","dateIssuedDisp":"1989-"}],"physDesc":[{"extent":"Online-Ressource"}],"title":[{"title":"Journal of physics","title_sort":"Journal of physics","partname":"Condensed matter"}],"titleAlt":[{"title":"Journal of physics / Condensed matter"}],"part":{"issue":"37","pages":"1-10","year":"2010","extent":"10","text":"22(2010), 37, Artikel-ID 375402, Seite 1-10","volume":"22"},"pubHistory":["1.1989 -"],"recId":"268759936","language":["eng"],"type":{"media":"Online-Ressource","bibl":"periodical"},"disp":"Structural stability of a golden semiconducting orthorhombic polymorph of Ti2O3 under high pressures and high temperaturesJournal of physics. Condensed matter","note":["Gesehen am 11.04.2022"]}],"physDesc":[{"extent":"10 S."}],"title":[{"title_sort":"Structural stability of a golden semiconducting orthorhombic polymorph of Ti2O3 under high pressures and high temperatures","title":"Structural stability of a golden semiconducting orthorhombic polymorph of Ti2O3 under high pressures and high temperatures"}],"person":[{"given":"Sergey","family":"Ovsyannikov","role":"aut","display":"Ovsyannikov, Sergey","roleDisplay":"VerfasserIn"},{"role":"aut","roleDisplay":"VerfasserIn","display":"Wu, Xiang","given":"Xiang","family":"Wu"},{"roleDisplay":"VerfasserIn","display":"Shchennikov, Vladimir V.","role":"aut","family":"Shchennikov","given":"Vladimir V."},{"family":"Karkin","given":"Alexander E.","display":"Karkin, Alexander E.","roleDisplay":"VerfasserIn","role":"aut"},{"role":"aut","roleDisplay":"VerfasserIn","display":"Dubrovinskaia, Natalia","given":"Natalia","family":"Dubrovinskaia"},{"family":"Garbarino","given":"Gaston","display":"Garbarino, Gaston","roleDisplay":"VerfasserIn","role":"aut"},{"display":"Dubrovinsky, Leonid","roleDisplay":"VerfasserIn","role":"aut","family":"Dubrovinsky","given":"Leonid"}],"titleAlt":[{"title":"Structural stability of a golden semiconducting orthorhombic polymorph of Ti 2 O 3 under high pressures and high temperatures"}],"recId":"185071357X","language":["eng"],"type":{"media":"Online-Ressource","bibl":"article-journal"},"note":["Im Text sind \"2\" und \"3\" tiefgestellt","Gesehen am 21.06.2023"]} | ||
| SRT | |a OVSYANNIKOSTRUCTURAL3120 | ||