Buchumschlag

μ3-Oxido-tris­{dichlorido[1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]gold(III)} bis­(trifluoro­methane­sulfon­yl)imide-[bis­(trifluoro­methane­sulfon­yl)imide]­silver(I) (1/2)

The unusual trinuclear AuIII oxide title complex, [Au3Cl6O(C21H24N2)3](C2F6NO4S2)·2[Ag(C2F6NO4S2)], is the side product of the reaction of [1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridophenyl­gold(III) with silver bis­(trifluoro­methane­sulfon­yl)imide in the presence of traces of...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Pažický, Marek (VerfasserIn) , Rominger, Frank (VerfasserIn) , Limbach, Michael (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 5 June 2010
In: Acta crystallographica. Section E, Structure reports online
Year: 2010, Jahrgang: 66, Heft: 7, Pages: m724-m725
ISSN:1600-5368
DOI:10.1107/S160053681001994X
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1107/S160053681001994X
Verlag, lizenzpflichtig, Volltext: https://scripts.iucr.org/cgi-bin/paper?hg2690
Volltext
Verfasserangaben:Marek Pažický, Frank Rominger and Michael Limbach

MARC

LEADER 00000caa a2200000 c 4500
001 1851311742
003 DE-627
005 20230710124852.0
007 cr uuu---uuuuu
008 230630s2010 xx |||||o 00| ||eng c
024 7 |a 10.1107/S160053681001994X  |2 doi 
035 |a (DE-627)1851311742 
035 |a (DE-599)KXP1851311742 
035 |a (OCoLC)1389793754 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Pažický, Marek  |e VerfasserIn  |0 (DE-588)1294223801  |0 (DE-627)1851185542  |4 aut 
245 1 0 |a μ3-Oxido-tris­{dichlorido[1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]gold(III)} bis­(trifluoro­methane­sulfon­yl)imide-[bis­(trifluoro­methane­sulfon­yl)imide]­silver(I) (1/2)  |c Marek Pažický, Frank Rominger and Michael Limbach 
246 3 3 |a Mu 3 - Oxido-tris­{dichlorido[1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]gold(III)} bis­(trifluoro­methane­sulfon­yl)imide-[bis­(trifluoro­methane­sulfon­yl)imide]­silver(I) (1/2) 
264 1 |c 5 June 2010 
300 |a 2 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Im Text ist "3" tiefgestellt 
500 |a Gesehen am 30.06.2023 
520 |a The unusual trinuclear AuIII oxide title complex, [Au3Cl6O(C21H24N2)3](C2F6NO4S2)·2[Ag(C2F6NO4S2)], is the side product of the reaction of [1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridophenyl­gold(III) with silver bis­(trifluoro­methane­sulfon­yl)imide in the presence of traces of water. In contrast to corresponding AuI complexes, the core structure of the title compound is planar. Two silver(I) bis­(trifluoro­methane­sulfon­yl)imide units are loosely bound to the complex cation. Here the silver atoms, disordered over two positions in a 0.870 (2):0.130 (2) ratio, inter­act either with the lone pairs of three chlorine ligands or two chlorine ligands and one edge of the mesityl π-system. The crystal under investigation was a partial racemic twin. 
700 1 |a Rominger, Frank  |d 1964-  |e VerfasserIn  |0 (DE-588)1019978228  |0 (DE-627)691067821  |0 (DE-576)359202756  |4 aut 
700 1 |a Limbach, Michael  |d 1976-  |e VerfasserIn  |0 (DE-588)131482955  |0 (DE-627)509808689  |0 (DE-576)298536536  |4 aut 
773 0 8 |i Enthalten in  |t Acta crystallographica. Section E, Structure reports online  |d Chester : International Union of Crystallography, 2001  |g 66(2010), 7, Seite m724-m725  |w (DE-627)326977392  |w (DE-600)2041947-8  |w (DE-576)094140308  |x 1600-5368  |7 nnas  |a μ3-Oxido-tris­{dichlorido[1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]gold(III)} bis­(trifluoro­methane­sulfon­yl)imide-[bis­(trifluoro­methane­sulfon­yl)imide]­silver(I) (1/2) 
773 1 8 |g volume:66  |g year:2010  |g number:7  |g pages:m724-m725  |g extent:2  |a μ3-Oxido-tris­{dichlorido[1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]gold(III)} bis­(trifluoro­methane­sulfon­yl)imide-[bis­(trifluoro­methane­sulfon­yl)imide]­silver(I) (1/2) 
856 4 0 |u https://doi.org/10.1107/S160053681001994X  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://scripts.iucr.org/cgi-bin/paper?hg2690  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20230630 
993 |a Article 
994 |a 2010 
998 |g 131482955  |a Limbach, Michael  |m 131482955:Limbach, Michael  |p 3  |y j 
998 |g 1019978228  |a Rominger, Frank  |m 1019978228:Rominger, Frank  |d 120000  |d 120100  |e 120000PR1019978228  |e 120100PR1019978228  |k 0/120000/  |k 1/120000/120100/  |p 2 
998 |g 1294223801  |a Pažický, Marek  |m 1294223801:Pažický, Marek  |d 850000  |d 852400  |d 120000  |d 120100  |e 850000PP1294223801  |e 852400PP1294223801  |e 120000PP1294223801  |e 120100PP1294223801  |k 0/850000/  |k 1/850000/852400/  |k 0/120000/  |k 1/120000/120100/  |p 1  |x j 
999 |a KXP-PPN1851311742  |e 4344877284 
BIB |a Y 
SER |a journal 
JSO |a {"id":{"doi":["10.1107/S160053681001994X"],"eki":["1851311742"]},"type":{"media":"Online-Ressource","bibl":"article-journal"},"physDesc":[{"extent":"2 S."}],"note":["Im Text ist \"3\" tiefgestellt","Gesehen am 30.06.2023"],"relHost":[{"id":{"zdb":["2041947-8"],"doi":["10.1107/S16005368"],"issn":["1600-5368"],"eki":["326977392"]},"part":{"text":"66(2010), 7, Seite m724-m725","volume":"66","pages":"m724-m725","year":"2010","issue":"7","extent":"2"},"note":["Gesehen am 24.01.17"],"origin":[{"publisher":"International Union of Crystallography ; Wiley-Blackwell","dateIssuedDisp":"h[2001-2014]","publisherPlace":"Chester ; Oxford"}],"name":{"displayForm":["International Union of Crystallography"]},"corporate":[{"display":"Internationale Union für Kristallographie","role":"isb"}],"title":[{"title_sort":"Acta crystallographica","partname":"Structure reports online","title":"Acta crystallographica"}],"pubHistory":["57.2001 - 70.2014"],"type":{"bibl":"periodical","media":"Online-Ressource"},"disp":"μ3-Oxido-tris­{dichlorido[1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]gold(III)} bis­(trifluoro­methane­sulfon­yl)imide-[bis­(trifluoro­methane­sulfon­yl)imide]­silver(I) (1/2)Acta crystallographica. Section E, Structure reports online","recId":"326977392","titleAlt":[{"title":"Acta crystallographica / E"}],"language":["eng"]}],"name":{"displayForm":["Marek Pažický, Frank Rominger and Michael Limbach"]},"origin":[{"dateIssuedKey":"2010","dateIssuedDisp":"5 June 2010"}],"recId":"1851311742","person":[{"family":"Pažický","display":"Pažický, Marek","given":"Marek","role":"aut"},{"role":"aut","family":"Rominger","display":"Rominger, Frank","given":"Frank"},{"role":"aut","family":"Limbach","given":"Michael","display":"Limbach, Michael"}],"titleAlt":[{"title":"Mu 3 - Oxido-tris­{dichlorido[1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]gold(III)} bis­(trifluoro­methane­sulfon­yl)imide-[bis­(trifluoro­methane­sulfon­yl)imide]­silver(I) (1/2)"}],"title":[{"title":"μ3-Oxido-tris­{dichlorido[1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]gold(III)} bis­(trifluoro­methane­sulfon­yl)imide-[bis­(trifluoro­methane­sulfon­yl)imide]­silver(I) (1/2)","title_sort":"μ3-Oxido-tris­{dichlorido[1,3-bis­(1,3,5-trimethyl­phen­yl)imidazol-2-yl­idene]gold(III)} bis­(trifluoro­methane­sulfon­yl)imide-[bis­(trifluoro­methane­sulfon­yl)imide]­silver(I) (1/2)"}],"language":["eng"]} 
SRT |a PAZICKYMAR3OXIDOTRIS5201 

Ähnliche Einträge