Cationic η3-allyl sulfide complexes of nickel(II) for the polymerization of butadiene in aqueous emulsion
Reaction of the dimeric allyl-nickel(II) chloro complex [Ni(η3-C3H5)(μ-Cl)]2 (5) with sulfur donor ligands (L=L10-L13) in the presence of NaBAr4F (Ar4F=3,5-(CF3)2C6H3) gives the corresponding cationic mononuclear complexes of the type [Ni(η3-C3H5)(L)2]+ (1-4) [L=L10=diphenyl sulfide (1); L=L11=4,4′-...
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| Hauptverfasser: | , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2010
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| In: |
Journal of organometallic chemistry
Year: 2010, Jahrgang: 695, Heft: 5, Pages: 673-679 |
| ISSN: | 1872-8561 |
| DOI: | 10.1016/j.jorganchem.2009.11.041 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jorganchem.2009.11.041 Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0022328X09007839 
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| Verfasserangaben: | Govindaswamy Padavattan, Christoph Jäkel, Tobias Steinke, Valentine Reimer, M. Belén Díaz-Valenzuela, Patrick Crewdson, Frank Rominger |
MARC
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| 245 | 1 | 0 | |a Cationic η3-allyl sulfide complexes of nickel(II) for the polymerization of butadiene in aqueous emulsion |c Govindaswamy Padavattan, Christoph Jäkel, Tobias Steinke, Valentine Reimer, M. Belén Díaz-Valenzuela, Patrick Crewdson, Frank Rominger |
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| 520 | |a Reaction of the dimeric allyl-nickel(II) chloro complex [Ni(η3-C3H5)(μ-Cl)]2 (5) with sulfur donor ligands (L=L10-L13) in the presence of NaBAr4F (Ar4F=3,5-(CF3)2C6H3) gives the corresponding cationic mononuclear complexes of the type [Ni(η3-C3H5)(L)2]+ (1-4) [L=L10=diphenyl sulfide (1); L=L11=4,4′-thiodiphenol (2); L=L12=4,4′-thio-bis(6-tert-butyl-o-cresol) (3); L=L13=4,4′-thio-bis (6-tert-butyl-m-cresol) (4)]. All of these complexes were characterized by elemental analysis and NMR spectroscopy, as well as the representative complex 3 additionally by single-crystal X-ray analysis. In comparison to the known complex [Ni(η3-C3H5)(η6-BHT)][BAr4F] (BHT=3,5-di-tert-butyl-4-hydroxytoluene), the herein described cationic complexes show an increased stability towards water. The activity of the complexes for butadiene polymerization in aqueous emulsions was studied. | ||
| 650 | 4 | |a Butadiene | |
| 650 | 4 | |a Catalytic polymerization | |
| 650 | 4 | |a Emulsion polymerization | |
| 650 | 4 | |a Nickel | |
| 650 | 4 | |a Sulfur ligands | |
| 700 | 1 | |a Jäkel, Christoph |d 1971- |e VerfasserIn |0 (DE-588)123053188 |0 (DE-627)082318387 |0 (DE-576)293535388 |4 aut | |
| 700 | 1 | |a Steinke, Tobias |e VerfasserIn |4 aut | |
| 700 | 1 | |a Reimer, Valentine |e VerfasserIn |4 aut | |
| 700 | 1 | |a Díaz-Valenzuela, Maria Belén |e VerfasserIn |4 aut | |
| 700 | 1 | |a Crewdson, Patrick |e VerfasserIn |4 aut | |
| 700 | 1 | |a Rominger, Frank |d 1964- |e VerfasserIn |0 (DE-588)1019978228 |0 (DE-627)691067821 |0 (DE-576)359202756 |4 aut | |
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