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Enantio- and regioselective iridium-catalyzed allylic hydroxylation

The first enantioselective allylic hydroxylation to prepare branched allylic alcohols directly is described. Bicarbonate was used as nucleophile in conjunction with new single component Ir-catalysts, which are stable to air and water. Excellent regio- and enantioselectivities have been achieved with...

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Bibliographic Details
Main Authors: Gärtner, Martin (Author) , Mader, Steffen (Author) , Seehafer, Kai (Author) , Helmchen, Günter (Author)
Format: Article (Journal)
Language:English
Published: January 28, 2011
In: Journal of the American Chemical Society
Year: 2011, Volume: 133, Issue: 7, Pages: 2072-2075
ISSN:1520-5126
DOI:10.1021/ja109953v
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ja109953v
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Author Notes:Martin Gärtner, Steffen Mader, Kai Seehafer, and Günter Helmchen
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Summary:The first enantioselective allylic hydroxylation to prepare branched allylic alcohols directly is described. Bicarbonate was used as nucleophile in conjunction with new single component Ir-catalysts, which are stable to air and water. Excellent regio- and enantioselectivities have been achieved with a representative set of substrates.
Item Description:Gesehen am 07.08.2023
Physical Description:Online Resource
ISSN:1520-5126
DOI:10.1021/ja109953v

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