Enantio- and regioselective iridium-catalyzed allylic hydroxylation
The first enantioselective allylic hydroxylation to prepare branched allylic alcohols directly is described. Bicarbonate was used as nucleophile in conjunction with new single component Ir-catalysts, which are stable to air and water. Excellent regio- and enantioselectivities have been achieved with...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
January 28, 2011
|
| In: |
Journal of the American Chemical Society
Year: 2011, Volume: 133, Issue: 7, Pages: 2072-2075 |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/ja109953v |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ja109953v
|
| Author Notes: | Martin Gärtner, Steffen Mader, Kai Seehafer, and Günter Helmchen |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1854471791 | ||
| 003 | DE-627 | ||
| 005 | 20240311114802.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 230807s2011 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/ja109953v |2 doi | |
| 035 | |a (DE-627)1854471791 | ||
| 035 | |a (DE-599)KXP1854471791 | ||
| 035 | |a (OCoLC)1425872041 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Gärtner, Martin |e VerfasserIn |0 (DE-588)1019566116 |0 (DE-627)690949782 |0 (DE-576)358349168 |4 aut | |
| 245 | 1 | 0 | |a Enantio- and regioselective iridium-catalyzed allylic hydroxylation |c Martin Gärtner, Steffen Mader, Kai Seehafer, and Günter Helmchen |
| 246 | 3 | 0 | |a Enantioselective |
| 264 | 1 | |c January 28, 2011 | |
| 300 | |a 4 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 07.08.2023 | ||
| 520 | |a The first enantioselective allylic hydroxylation to prepare branched allylic alcohols directly is described. Bicarbonate was used as nucleophile in conjunction with new single component Ir-catalysts, which are stable to air and water. Excellent regio- and enantioselectivities have been achieved with a representative set of substrates. | ||
| 700 | 1 | |a Mader, Steffen |d 1987- |e VerfasserIn |0 (DE-588)115482103X |0 (DE-627)1016192436 |0 (DE-576)501261974 |4 aut | |
| 700 | 1 | |a Seehafer, Kai |e VerfasserIn |0 (DE-588)1071924818 |0 (DE-627)826643590 |0 (DE-576)433440104 |4 aut | |
| 700 | 1 | |a Helmchen, Günter |e VerfasserIn |0 (DE-588)115539689 |0 (DE-627)691390134 |0 (DE-576)289938902 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |a American Chemical Society |t Journal of the American Chemical Society |d Washington, DC : ACS Publications, 1879 |g 133(2011), 7 vom: Feb., Seite 2072-2075 |w (DE-627)268132836 |w (DE-600)1472210-0 |w (DE-576)090854284 |x 1520-5126 |7 nnas |
| 773 | 1 | 8 | |g volume:133 |g year:2011 |g number:7 |g month:02 |g pages:2072-2075 |g extent:4 |a Enantio- and regioselective iridium-catalyzed allylic hydroxylation |
| 856 | 4 | 0 | |u https://doi.org/10.1021/ja109953v |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20230807 | ||
| 993 | |a Article | ||
| 994 | |a 2011 | ||
| 998 | |g 115539689 |a Helmchen, Günter |m 115539689:Helmchen, Günter |d 120000 |d 120100 |e 120000PH115539689 |e 120100PH115539689 |k 0/120000/ |k 1/120000/120100/ |p 4 |y j | ||
| 998 | |g 1071924818 |a Seehafer, Kai |m 1071924818:Seehafer, Kai |d 120000 |e 120000PS1071924818 |k 0/120000/ |p 3 | ||
| 998 | |g 115482103X |a Mader, Steffen |m 115482103X:Mader, Steffen |d 120000 |e 120000PM115482103X |k 0/120000/ |p 2 | ||
| 998 | |g 1019566116 |a Gärtner, Martin |m 1019566116:Gärtner, Martin |d 120000 |e 120000PG1019566116 |k 0/120000/ |p 1 |x j | ||
| 999 | |a KXP-PPN1854471791 |e 4363533811 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"note":["Gesehen am 07.08.2023"],"type":{"media":"Online-Ressource","bibl":"article-journal"},"language":["eng"],"recId":"1854471791","person":[{"family":"Gärtner","given":"Martin","display":"Gärtner, Martin","roleDisplay":"VerfasserIn","role":"aut"},{"display":"Mader, Steffen","roleDisplay":"VerfasserIn","role":"aut","family":"Mader","given":"Steffen"},{"family":"Seehafer","given":"Kai","roleDisplay":"VerfasserIn","display":"Seehafer, Kai","role":"aut"},{"role":"aut","display":"Helmchen, Günter","roleDisplay":"VerfasserIn","given":"Günter","family":"Helmchen"}],"title":[{"title_sort":"Enantio- and regioselective iridium-catalyzed allylic hydroxylation","title":"Enantio- and regioselective iridium-catalyzed allylic hydroxylation"}],"physDesc":[{"extent":"4 S."}],"relHost":[{"title":[{"subtitle":"JACS","title":"Journal of the American Chemical Society","title_sort":"Journal of the American Chemical Society"}],"disp":"American Chemical SocietyJournal of the American Chemical Society","note":["Gesehen am 25.08.2020"],"type":{"media":"Online-Ressource","bibl":"periodical"},"corporate":[{"roleDisplay":"VerfasserIn","display":"American Chemical Society","role":"aut"}],"language":["eng"],"recId":"268132836","pubHistory":["1.1879 -"],"part":{"extent":"4","volume":"133","text":"133(2011), 7 vom: Feb., Seite 2072-2075","issue":"7","pages":"2072-2075","year":"2011"},"titleAlt":[{"title":"JACS"},{"title":"web edition"}],"name":{"displayForm":["Ed.: Allen J. Bard [u.a.]"]},"origin":[{"publisherPlace":"Washington, DC ; Washington, DC","dateIssuedDisp":"1879-","dateIssuedKey":"1879","publisher":"ACS Publications ; American Chemical Society"}],"id":{"issn":["1520-5126"],"zdb":["1472210-0"],"eki":["268132836"]}}],"name":{"displayForm":["Martin Gärtner, Steffen Mader, Kai Seehafer, and Günter Helmchen"]},"origin":[{"dateIssuedKey":"2011","dateIssuedDisp":"January 28, 2011"}],"id":{"eki":["1854471791"],"doi":["10.1021/ja109953v"]}} | ||
| SRT | |a GAERTNERMAENANTIOAND2820 | ||