Cover Image

Ferro- and ferrielectricity and negative piezoelectricity in thioamide-based supramolecular organic discotics

Amide-based discotic supramolecular organic materials are of interest for fundamental understanding of cooperative self-assembly and collective dipole switching mechanisms as well as for practically relevant ferroelectric and piezoelectric properties. Here, we show how replacing amides (dipole momen...

Full description

Saved in:
Bibliographic Details
Main Authors: Urbanavičiūtė, Indrė (Author) , Garcia-Iglesias, Miguel (Author) , Gorbunov, Andrey (Author) , Meijer, E. W. (Author) , Kemerink, Martijn (Author)
Format: Article (Journal)
Language:English
Published: 2023
In: Physical chemistry, chemical physics
Year: 2023, Volume: 25, Issue: 25, Pages: 16930-16937
ISSN:1463-9084
DOI:10.1039/D3CP00982C
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D3CP00982C
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2023/cp/d3cp00982c
Get full text
Author Notes:Indre Urbanaviciute, Miguel Garcia-Iglesias, Andrey Gorbunov, E.W. Meijer and Martijn Kemerink

MARC

LEADER 00000caa a2200000 c 4500
001 185499557X
003 DE-627
005 20240307062344.0
007 cr uuu---uuuuu
008 230809s2023 xx |||||o 00| ||eng c
024 7 |a 10.1039/D3CP00982C  |2 doi 
035 |a (DE-627)185499557X 
035 |a (DE-599)KXP185499557X 
035 |a (OCoLC)1425213173 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 29  |2 sdnb 
100 1 |a Urbanavičiūtė, Indrė  |e VerfasserIn  |0 (DE-588)1200382099  |0 (DE-627)168338041X  |4 aut 
245 1 0 |a Ferro- and ferrielectricity and negative piezoelectricity in thioamide-based supramolecular organic discotics  |c Indre Urbanaviciute, Miguel Garcia-Iglesias, Andrey Gorbunov, E.W. Meijer and Martijn Kemerink 
264 1 |c 2023 
300 |b Illustrationen 
300 |a 8 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Veröffentlicht: 13. Juni 2023 
500 |a Gesehen am 09.08.2023 
520 |a Amide-based discotic supramolecular organic materials are of interest for fundamental understanding of cooperative self-assembly and collective dipole switching mechanisms as well as for practically relevant ferroelectric and piezoelectric properties. Here, we show how replacing amides (dipole moment of ∼3.5 D) with thioamides (∼5.1 D) as dipolar moieties in the archetypal C3-symmetric discotic molecule BTA leads to ferroelectric materials with a higher remnant polarization and lower coercive field. The thioamide-based materials also demonstrate a rare negative piezoelectricity and a previously predicted, yet never experimentally observed, polarization reversal via asymmetric intermediate states, that is, ferrielectric switching. 
700 1 |a Garcia-Iglesias, Miguel  |e VerfasserIn  |4 aut 
700 1 |a Gorbunov, Andrey  |e VerfasserIn  |4 aut 
700 1 |a Meijer, E. W.  |e VerfasserIn  |4 aut 
700 1 |a Kemerink, Martijn  |e VerfasserIn  |0 (DE-588)1200360753  |0 (DE-627)1683330668  |4 aut 
773 0 8 |i Enthalten in  |t Physical chemistry, chemical physics  |d Cambridge : RSC Publ., 1999  |g 25(2023), 25, Seite 16930-16937  |h Online-Ressource  |w (DE-627)270125175  |w (DE-600)1476244-4  |w (DE-576)080160328  |x 1463-9084  |7 nnas  |a Ferro- and ferrielectricity and negative piezoelectricity in thioamide-based supramolecular organic discotics 
773 1 8 |g volume:25  |g year:2023  |g number:25  |g pages:16930-16937  |g extent:8  |a Ferro- and ferrielectricity and negative piezoelectricity in thioamide-based supramolecular organic discotics 
856 4 0 |u https://doi.org/10.1039/D3CP00982C  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://pubs.rsc.org/en/content/articlelanding/2023/cp/d3cp00982c  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20230809 
993 |a Article 
994 |a 2023 
998 |g 1200360753  |a Kemerink, Martijn  |m 1200360753:Kemerink, Martijn  |d 160000  |d 160200  |e 160000PK1200360753  |e 160200PK1200360753  |k 0/160000/  |k 1/160000/160200/  |p 5  |y j 
999 |a KXP-PPN185499557X  |e 4364135925 
BIB |a Y 
SER |a journal 
JSO |a {"title":[{"title":"Ferro- and ferrielectricity and negative piezoelectricity in thioamide-based supramolecular organic discotics","title_sort":"Ferro- and ferrielectricity and negative piezoelectricity in thioamide-based supramolecular organic discotics"}],"person":[{"family":"Urbanavičiūtė","given":"Indrė","roleDisplay":"VerfasserIn","display":"Urbanavičiūtė, Indrė","role":"aut"},{"family":"Garcia-Iglesias","given":"Miguel","roleDisplay":"VerfasserIn","display":"Garcia-Iglesias, Miguel","role":"aut"},{"given":"Andrey","family":"Gorbunov","role":"aut","display":"Gorbunov, Andrey","roleDisplay":"VerfasserIn"},{"given":"E. W.","family":"Meijer","role":"aut","display":"Meijer, E. W.","roleDisplay":"VerfasserIn"},{"display":"Kemerink, Martijn","roleDisplay":"VerfasserIn","role":"aut","family":"Kemerink","given":"Martijn"}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"note":["Veröffentlicht: 13. Juni 2023","Gesehen am 09.08.2023"],"recId":"185499557X","language":["eng"],"origin":[{"dateIssuedKey":"2023","dateIssuedDisp":"2023"}],"id":{"eki":["185499557X"],"doi":["10.1039/D3CP00982C"]},"name":{"displayForm":["Indre Urbanaviciute, Miguel Garcia-Iglesias, Andrey Gorbunov, E.W. Meijer and Martijn Kemerink"]},"physDesc":[{"noteIll":"Illustrationen","extent":"8 S."}],"relHost":[{"corporate":[{"role":"isb","roleDisplay":"Herausgebendes Organ","display":"Royal Society of Chemistry"}],"language":["eng"],"recId":"270125175","note":["Gesehen am 20.02.24"],"disp":"Ferro- and ferrielectricity and negative piezoelectricity in thioamide-based supramolecular organic discoticsPhysical chemistry, chemical physics","type":{"bibl":"periodical","media":"Online-Ressource"},"part":{"volume":"25","text":"25(2023), 25, Seite 16930-16937","extent":"8","year":"2023","issue":"25","pages":"16930-16937"},"titleAlt":[{"title":"PCCP"}],"pubHistory":["1.1999 -"],"title":[{"title_sort":"Physical chemistry, chemical physics","subtitle":"PCCP ; a journal of European chemical societies","title":"Physical chemistry, chemical physics"}],"physDesc":[{"extent":"Online-Ressource"}],"name":{"displayForm":["RSC, Royal Society of Chemistry"]},"id":{"eki":["270125175"],"zdb":["1476244-4"],"issn":["1463-9084"]},"origin":[{"publisherPlace":"Cambridge","dateIssuedKey":"1999","publisher":"RSC Publ.","dateIssuedDisp":"1999-"}]}]} 
SRT |a URBANAVICIFERROANDFE2023 

Similar Items