Single crystals of insoluble porous salicylimine cages [data]
Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorp...
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| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Datenbank Forschungsdaten |
| Sprache: | Englisch |
| Veröffentlicht: |
Heidelberg
Universität
2023-08-23
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| DOI: | 10.11588/data/45FZRY |
| Schlagworte: | |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.11588/data/45FZRY Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/45FZRY |
| Verfasserangaben: | Mattes Holsten, Sven Michael Elbert, Frank Rominger, Wen-Shan Zhang, Rasmus R. Schröder, Michael Mastalerz |
| Zusammenfassung: | Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorphous materials. These cages were now synthesized as single-crystalline materials to get insight into packing motifs and preferred intermolecular interactions. Furthermore, the pairs of crystalline and amorphous materials for each cage allowed to compare their gas-sorption properties in both morphological states. |
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| Beschreibung: | Gesehen am 24.08.2023 |
| Beschreibung: | Online Resource |
| DOI: | 10.11588/data/45FZRY |