Single crystals of insoluble porous salicylimine cages
Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorp...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
November 24, 2023
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| In: |
Chemistry - a European journal
Year: 2023, Volume: 29, Issue: 66, Pages: 1-10 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.202302116 |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/chem.202302116 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202302116 
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| Author Notes: | Mattes Holsten, Sven M. Elbert, Frank Rominger, Wen-Shan Zhang, Rasmus R. Schröder, and Michael Mastalerz |
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| 520 | |a Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorphous materials. These cages were now synthesized as single-crystalline materials to get insight into packing motifs and preferred intermolecular interactions. Furthermore, the pairs of crystalline and amorphous materials for each cage allowed to compare their gas-sorption properties in both morphological states. | ||
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