Solvent-controlled quadruple catenation of giant chiral (8+12) salicylimine cubes driven by weak hydrogen bonding [data]
A quadruply interlocked catenane has been formed from giant chiral [8+12] salicylimine cubes in a reaction that can be controlled by the reaction solvent. Single-crystal X-ray diffraction revealed hydrogen bonding to be a central driving force for the catenation. Furthermore, scrambling experiments...
Gespeichert in:
| Hauptverfasser: | , , , |
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| Dokumenttyp: | Datenbank Forschungsdaten |
| Sprache: | Englisch |
| Veröffentlicht: |
Heidelberg
Universität
2023-08-23
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| DOI: | 10.11588/data/TIYBD2 |
| Schlagworte: | |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.11588/data/TIYBD2 Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/TIYBD2 
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| Verfasserangaben: | Philippe Wagner, Frank Rominger, Jürgen H. Gross, Michael Mastalerz |
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| 520 | |a A quadruply interlocked catenane has been formed from giant chiral [8+12] salicylimine cubes in a reaction that can be controlled by the reaction solvent. Single-crystal X-ray diffraction revealed hydrogen bonding to be a central driving force for the catenation. Furthermore, scrambling experiments with partially deuterated cages allowed mechanistic insights into the interlocking process. | ||
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| 787 | 0 | 8 | |i Forschungsdaten zu |a Wagner, Philippe, 1991 - |t Solvent-controlled quadruple catenation of giant chiral (8+12) salicylimine cubes driven by weak hydrogen bonding |d 2023 |w (DE-627)1857901002 |
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