Loops versus stems: benzylic sulfide oligomers forming carpet type monolayers
Chainlike oligomers consisting of several meta position interlinked benzylic sulfides and terminal benzylic thiols were synthesized, and the nature of the molecular monolayers formed by their self-assembly on gold (111) substrates was investigated. The fabricated films were characterized by high-res...
Gespeichert in:
| Hauptverfasser: | , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
17 February 2010
|
| In: |
The journal of physical chemistry. C, Energy, materials, and catalysis
Year: 2010, Jahrgang: 114, Heft: 9, Pages: 4118-4125 |
| ISSN: | 1932-7455 |
| DOI: | 10.1021/jp911879x |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jp911879x
|
| Verfasserangaben: | Fabian Sander, Torsten Peterle, Nirmalya Ballav, Florian von Wrochem, Michael Zharnikov, and Marcel Mayor |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1857972228 | ||
| 003 | DE-627 | ||
| 005 | 20240311125503.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 230825s2010 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/jp911879x |2 doi | |
| 035 | |a (DE-627)1857972228 | ||
| 035 | |a (DE-599)KXP1857972228 | ||
| 035 | |a (OCoLC)1425874255 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Sander, Fabian |d 1982- |e VerfasserIn |0 (DE-588)1065268912 |0 (DE-627)815789327 |0 (DE-576)424941139 |4 aut | |
| 245 | 1 | 0 | |a Loops versus stems |b benzylic sulfide oligomers forming carpet type monolayers |c Fabian Sander, Torsten Peterle, Nirmalya Ballav, Florian von Wrochem, Michael Zharnikov, and Marcel Mayor |
| 264 | 1 | |c 17 February 2010 | |
| 300 | |a 8 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 25.08.2023 | ||
| 520 | |a Chainlike oligomers consisting of several meta position interlinked benzylic sulfides and terminal benzylic thiols were synthesized, and the nature of the molecular monolayers formed by their self-assembly on gold (111) substrates was investigated. The fabricated films were characterized by high-resolution X-ray photoelectron spectroscopy and near-edge X-ray absorption fine structure spectroscopy. In the case of the short oligomers, the spectroscopic studies were additionally supported by scanning tunneling microscopy experiments. The target molecules were found to form dense and contamination-free self-assembled monolayer (SAM)-like “carpet” films on gold (111). In spite of the multidentate nature of the benzylic sulfide oligomers, the predominant molecular conformation in these films were bridges (“loops”) formed by the covalent attachment of both terminal thiols with a minor amount of molecules which were bound by only one thiol group as upright standing “stems” protruding the SAM. The films exhibited only a limited degree of order with slight preference of a perpendicular-to-the-surface orientation of the individual phenyl rings of the oligomer chains. | ||
| 700 | 1 | |a Peterle, Torsten |e VerfasserIn |4 aut | |
| 700 | 1 | |a Ballav, Nirmalya |e VerfasserIn |0 (DE-588)1274138264 |0 (DE-627)1823890415 |4 aut | |
| 700 | 1 | |a Wrochem, Florian von |e VerfasserIn |4 aut | |
| 700 | 1 | |a Zharnikov, Michael |e VerfasserIn |0 (DE-588)1118537629 |0 (DE-627)872019810 |0 (DE-576)479525889 |4 aut | |
| 700 | 1 | |a Mayor, Marcel |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t The journal of physical chemistry. C, Energy, materials, and catalysis |d Washington, DC : Soc., 2007 |g 114(2010), 9, Seite 4118-4125 |h Online-Ressource |w (DE-627)519508645 |w (DE-600)2256522-X |w (DE-576)259487104 |x 1932-7455 |7 nnas |a Loops versus stems benzylic sulfide oligomers forming carpet type monolayers |
| 773 | 1 | 8 | |g volume:114 |g year:2010 |g number:9 |g pages:4118-4125 |g extent:8 |a Loops versus stems benzylic sulfide oligomers forming carpet type monolayers |
| 856 | 4 | 0 | |u https://doi.org/10.1021/jp911879x |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20230825 | ||
| 993 | |a Article | ||
| 994 | |a 2010 | ||
| 998 | |g 1118537629 |a Zharnikov, Michael |m 1118537629:Zharnikov, Michael |d 120000 |d 120300 |e 120000PZ1118537629 |e 120300PZ1118537629 |k 0/120000/ |k 1/120000/120300/ |p 5 | ||
| 998 | |g 1274138264 |a Ballav, Nirmalya |m 1274138264:Ballav, Nirmalya |d 120000 |d 120300 |e 120000PB1274138264 |e 120300PB1274138264 |k 0/120000/ |k 1/120000/120300/ |p 3 | ||
| 999 | |a KXP-PPN1857972228 |e 4370316790 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"person":[{"family":"Sander","role":"aut","given":"Fabian","display":"Sander, Fabian"},{"role":"aut","given":"Torsten","family":"Peterle","display":"Peterle, Torsten"},{"display":"Ballav, Nirmalya","family":"Ballav","given":"Nirmalya","role":"aut"},{"family":"Wrochem","given":"Florian von","role":"aut","display":"Wrochem, Florian von"},{"display":"Zharnikov, Michael","family":"Zharnikov","role":"aut","given":"Michael"},{"family":"Mayor","given":"Marcel","role":"aut","display":"Mayor, Marcel"}],"title":[{"title_sort":"Loops versus stems","subtitle":"benzylic sulfide oligomers forming carpet type monolayers","title":"Loops versus stems"}],"physDesc":[{"extent":"8 S."}],"language":["eng"],"type":{"bibl":"article-journal","media":"Online-Ressource"},"id":{"doi":["10.1021/jp911879x"],"eki":["1857972228"]},"origin":[{"dateIssuedDisp":"17 February 2010","dateIssuedKey":"2010"}],"name":{"displayForm":["Fabian Sander, Torsten Peterle, Nirmalya Ballav, Florian von Wrochem, Michael Zharnikov, and Marcel Mayor"]},"recId":"1857972228","note":["Gesehen am 25.08.2023"],"relHost":[{"pubHistory":["111.2007 -"],"titleAlt":[{"title":"The journal of physical chemistry <Washington, DC> / C"},{"title":"Nanomaterials and interfaces"},{"title":"JPC C"},{"title":"JPCC"}],"note":["Gesehen am 13.03.2023"],"part":{"volume":"114","pages":"4118-4125","extent":"8","text":"114(2010), 9, Seite 4118-4125","year":"2010","issue":"9"},"title":[{"partname":"Energy, materials, and catalysis","title_sort":"journal of physical chemistry","title":"The journal of physical chemistry"}],"language":["eng"],"physDesc":[{"extent":"Online-Ressource"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"corporate":[{"role":"isb","display":"American Chemical Society"}],"origin":[{"publisher":"Soc.","dateIssuedKey":"2007","dateIssuedDisp":"2007-","publisherPlace":"Washington, DC"}],"id":{"eki":["519508645"],"issn":["1932-7455"],"zdb":["2256522-X"]},"disp":"Loops versus stems benzylic sulfide oligomers forming carpet type monolayersThe journal of physical chemistry. C, Energy, materials, and catalysis","recId":"519508645","name":{"displayForm":["publ. weekly by the American Chemical Society"]}}]} | ||
| SRT | |a SANDERFABILOOPSVERSU1720 | ||