Cover Image

Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenes

Show other versions (1)

The palladium catalyzed cyclotrimerization of ortho-silylaryl triflates as aryne precursors is meanwhile an established method to synthesize polycyclic aromatic hydrocarbons (PAHs) with triphenylene cores. During the palladium-catalyzed reaction of a pyrene with an o-silylaryl triflate moiety in the...

Full description

Saved in:
Bibliographic Details
Main Authors: Popp, Dennis (Author) , Elbert, Sven (Author) , Barwig, Chantal (Author) , Petry, Julian (Author) , Rominger, Frank (Author) , Mastalerz, Michael (Author)
Format: Article (Journal)
Language:English
Published: May 2, 2023
In: Angewandte Chemie
Year: 2023, Volume: 135, Issue: 19
ISSN:1521-3757
DOI:10.1002/ange.202219277
Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/ange.202219277
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.202219277
Get full text
Author Notes:Dennis Popp, Sven M. Elbert, Chantal Barwig, Julian Petry, Frank Rominger, Michael Mastalerz

MARC

LEADER 00000caa a2200000 c 4500
001 1858742536
003 DE-627
005 20241205142257.0
007 cr uuu---uuuuu
008 230904s2023 xx |||||o 00| ||eng c
024 7 |a 10.1002/ange.202219277  |2 doi 
035 |a (DE-627)1858742536 
035 |a (DE-599)KXP1858742536 
035 |a (OCoLC)1425212416 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Popp, Dennis  |d 1993-  |e VerfasserIn  |0 (DE-588)1245484648  |0 (DE-627)1777151090  |4 aut 
245 1 0 |a Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenes  |c Dennis Popp, Sven M. Elbert, Chantal Barwig, Julian Petry, Frank Rominger, Michael Mastalerz 
264 1 |c May 2, 2023 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 04.09.2023 
520 |a The palladium catalyzed cyclotrimerization of ortho-silylaryl triflates as aryne precursors is meanwhile an established method to synthesize polycyclic aromatic hydrocarbons (PAHs) with triphenylene cores. During the palladium-catalyzed reaction of a pyrene with an o-silylaryl triflate moiety in the K-region higher homologues with central eight- and ten-membered rings (the pyrenylenes) were found, besides the expected trimer and a protocol was developed to isolate all members of this series. This unprecedented new class of PAHs was fully investigated by all means, including X-ray diffraction of single-crystals, UV/Vis and fluorescence spectroscopy and theoretical calculations. Supported by density-functional theory (DFT) calculations, a mechanism of all higher cyclooligomers is proposed. 
650 4 |a Aryne 
650 4 |a Macrocycles 
650 4 |a Palladium 
650 4 |a Polycyclic Aromatic Hydrocarbon 
650 4 |a Pyrene 
700 1 |a Elbert, Sven  |e VerfasserIn  |0 (DE-588)1161543546  |0 (DE-627)1024826341  |0 (DE-576)50671263X  |4 aut 
700 1 |a Barwig, Chantal  |d 1995-  |e VerfasserIn  |0 (DE-588)1274993164  |0 (DE-627)1826617981  |4 aut 
700 1 |a Petry, Julian  |d 1962-  |e VerfasserIn  |0 (DE-588)172822637  |0 (DE-627)697752631  |0 (DE-576)133678725  |4 aut 
700 1 |a Rominger, Frank  |d 1964-  |e VerfasserIn  |0 (DE-588)1019978228  |0 (DE-627)691067821  |0 (DE-576)359202756  |4 aut 
700 1 |a Mastalerz, Michael  |d 1972-  |e VerfasserIn  |0 (DE-588)130559431  |0 (DE-627)503822701  |0 (DE-576)298267950  |4 aut 
773 0 8 |i Enthalten in  |t Angewandte Chemie  |d Weinheim : Wiley-VCH, 1887  |g 135(2023), 19, Artikel-ID e202219277  |h Online-Ressource  |w (DE-627)271178531  |w (DE-600)1479266-7  |w (DE-576)078707463  |x 1521-3757  |7 nnas  |a Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenes 
773 1 8 |g volume:135  |g year:2023  |g number:19  |g elocationid:e202219277  |a Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenes 
775 0 8 |i Parallele Sprachausgabe  |n englisch  |a Popp, Dennis, 1993 -   |t Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenes  |d 2023  |w (DE-627)1857902246 
787 0 8 |i Forschungsdaten  |a Popp, Dennis, 1993 -   |t Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenes [data]  |d Heidelberg : Universität, 2023  |h 1 Online-Ressource (13 Files)  |w (DE-627)1857901568 
856 4 0 |u https://doi.org/10.1002/ange.202219277  |x Verlag  |x Resolving-System  |z kostenfrei  |3 Volltext 
856 4 0 |u https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.202219277  |x Verlag  |z kostenfrei  |3 Volltext 
951 |a AR 
992 |a 20230904 
993 |a Article 
994 |a 2023 
998 |g 130559431  |a Mastalerz, Michael  |m 130559431:Mastalerz, Michael  |d 120000  |d 120100  |e 120000PM130559431  |e 120100PM130559431  |k 0/120000/  |k 1/120000/120100/  |p 6  |y j 
998 |g 1019978228  |a Rominger, Frank  |m 1019978228:Rominger, Frank  |d 120000  |d 120100  |e 120000PR1019978228  |e 120100PR1019978228  |k 0/120000/  |k 1/120000/120100/  |p 5 
998 |g 172822637  |a Petry, Julian  |m 172822637:Petry, Julian  |p 4 
998 |g 1274993164  |a Barwig, Chantal  |m 1274993164:Barwig, Chantal  |d 160000  |d 160200  |e 160000PB1274993164  |e 160200PB1274993164  |k 0/160000/  |k 1/160000/160200/  |p 3 
998 |g 1161543546  |a Elbert, Sven  |m 1161543546:Elbert, Sven  |d 120000  |d 120100  |e 120000PE1161543546  |e 120100PE1161543546  |k 0/120000/  |k 1/120000/120100/  |p 2 
998 |g 1245484648  |a Popp, Dennis  |m 1245484648:Popp, Dennis  |d 120000  |d 120100  |e 120000PP1245484648  |e 120100PP1245484648  |k 0/120000/  |k 1/120000/120100/  |p 1  |x j 
999 |a KXP-PPN1858742536  |e 437233799X 
BIB |a Y 
SER |a journal 
JSO |a {"language":["eng"],"note":["Gesehen am 04.09.2023"],"type":{"bibl":"article-journal","media":"Online-Ressource"},"relHost":[{"id":{"doi":["10.1002/(ISSN)1521-3757"],"issn":["1521-3757"],"zdb":["1479266-7"],"eki":["271178531"]},"recId":"271178531","titleAlt":[{"title":"Zeitschrift für angewandte Chemie"},{"title":"Zeitschrift für angewandte Chemie und Zentralblatt für technische Chemie"},{"title":"Zeitschrift für angewandte Chemie"},{"title":"Angewandte Chemie"},{"title":"Die Chemie <Berlin>"},{"title":"Angewandte Chemie / A"}],"corporate":[{"role":"isb","display":"Gesellschaft Deutscher Chemiker"}],"part":{"issue":"19","year":"2023","text":"135(2023), 19, Artikel-ID e202219277","volume":"135"},"disp":"Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenesAngewandte Chemie","physDesc":[{"extent":"Online-Ressource"}],"language":["ger"],"pubHistory":["1.1887 -"],"title":[{"title":"Angewandte Chemie","title_sort":"Angewandte Chemie"}],"origin":[{"publisherPlace":"Weinheim","dateIssuedDisp":"1887-","publisher":"Wiley-VCH","dateIssuedKey":"1887"}],"type":{"media":"Online-Ressource","bibl":"periodical"},"note":["Gesehen am 30.01.04","Gesehen am 31.01.11","Fortsetzung der Druck-Ausgabe"]}],"name":{"displayForm":["Dennis Popp, Sven M. Elbert, Chantal Barwig, Julian Petry, Frank Rominger, Michael Mastalerz"]},"origin":[{"dateIssuedKey":"2023","dateIssuedDisp":"May 2, 2023"}],"recId":"1858742536","person":[{"display":"Popp, Dennis","given":"Dennis","family":"Popp","role":"aut"},{"role":"aut","given":"Sven","family":"Elbert","display":"Elbert, Sven"},{"family":"Barwig","given":"Chantal","display":"Barwig, Chantal","role":"aut"},{"role":"aut","given":"Julian","family":"Petry","display":"Petry, Julian"},{"family":"Rominger","given":"Frank","display":"Rominger, Frank","role":"aut"},{"display":"Mastalerz, Michael","given":"Michael","family":"Mastalerz","role":"aut"}],"title":[{"title_sort":"Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenes","title":"Palladium-catalyzed cyclization of a pyryne precursor to higher pyrenylenes"}],"id":{"doi":["10.1002/ange.202219277"],"eki":["1858742536"]}} 
SRT |a POPPDENNISPALLADIUMC2202 

Similar Items