Resonant X-ray emission spectroscopy of liquid water: Novel instrumentation, high resolution, and the “map” approach
Techniques to study the electronic structure of liquids are rare. Most recently, resonant X-ray emission spectroscopy (XES) has been shown to be an extremely versatile spectroscopy to study both occupied and unoccupied electronic states for liquids in thermodynamic equilibrium. However, XES requires...
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| Hauptverfasser: | , , , , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2010
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| In: |
Journal of electron spectroscopy and related phenomena
Year: 2010, Jahrgang: 177, Heft: 2/3, Pages: 206-211 |
| ISSN: | 0368-2048 |
| DOI: | 10.1016/j.elspec.2009.02.014 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.elspec.2009.02.014 Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0368204809000553 
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| Verfasserangaben: | L. Weinhardt, O. Fuchs, M. Blum, M. Bär, M. Weigand, J.D. Denlinger, Y. Zubavichus, M. Zharnikov, M. Grunze, C. Heske, E. Umbach |
MARC
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| 245 | 1 | 0 | |a Resonant X-ray emission spectroscopy of liquid water |b Novel instrumentation, high resolution, and the “map” approach |c L. Weinhardt, O. Fuchs, M. Blum, M. Bär, M. Weigand, J.D. Denlinger, Y. Zubavichus, M. Zharnikov, M. Grunze, C. Heske, E. Umbach |
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| 520 | |a Techniques to study the electronic structure of liquids are rare. Most recently, resonant X-ray emission spectroscopy (XES) has been shown to be an extremely versatile spectroscopy to study both occupied and unoccupied electronic states for liquids in thermodynamic equilibrium. However, XES requires high-brilliance soft X-ray synchrotron radiation and poses significant technical challenges to maintain a liquid sample in an ultra-high vacuum environment. Our group has therefore developed and constructed a novel experimental setup for the study of liquids, with the long-term goal of investigating the electronic structure of biological systems in aqueous environments. We have developed a flow-through liquid cell in which the liquid is separated from vacuum by a thin Si3N4 or SiC window and which allows a precise control of temperature. ... | ||
| 650 | 4 | |a High resolution | |
| 650 | 4 | |a Hydrogen bonds | |
| 650 | 4 | |a Liquids | |
| 650 | 4 | |a Water | |
| 650 | 4 | |a X-ray absorption | |
| 650 | 4 | |a X-ray emission | |
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| 700 | 1 | |a Denlinger, J. D. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Zubavichus, Yan |e VerfasserIn |0 (DE-588)1306579678 |0 (DE-627)1866376659 |4 aut | |
| 700 | 1 | |a Zharnikov, Michael |e VerfasserIn |0 (DE-588)1118537629 |0 (DE-627)872019810 |0 (DE-576)479525889 |4 aut | |
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| 700 | 1 | |a Heske, C. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Umbach, E. |e VerfasserIn |4 aut | |
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