On the coordination chemistry of triazolyl-substituted diborane ligands, prepared by 1,3-dipolar cycloaddition reactions between diazido-diboranes and alkynes
Metal-free cycloaddition reactions between a diazido-diborane and alkynes are used to synthesize new ditriazolyl-diborane molecules, a bis(ferrocenyl-1,2,3-triazolyl)-diborane and a bis(2-pyridyl-1,2,3-triazolyl)-diborane. Then, the bis(2-pyridyl-1,2,3-triazolyl)-diborane was used as polydentate lig...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
December 20, 2023
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| In: |
European journal of inorganic chemistry
Year: 2023, Jahrgang: 26, Heft: 36, Pages: 1-5 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.202300565 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/ejic.202300565 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.202300565 
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| Verfasserangaben: | Daniel Vogler, Maurice Schenker, Kim Hao Ng, Elisabeth Kaifer, and Hans-Jörg Himmel |
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| 520 | |a Metal-free cycloaddition reactions between a diazido-diborane and alkynes are used to synthesize new ditriazolyl-diborane molecules, a bis(ferrocenyl-1,2,3-triazolyl)-diborane and a bis(2-pyridyl-1,2,3-triazolyl)-diborane. Then, the bis(2-pyridyl-1,2,3-triazolyl)-diborane was used as polydentate ligand for the synthesis of larger architectures. Reaction with ditriflato-diborane yielded a tetracationic hexaboron compound, and reaction with metal salts yielded dicationic ring compounds with two hexacoordinate metal atoms and two integrated diborane units. | ||
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