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Neutral and anionic square planar palladium(0) complexes stabilized by a silicon Z-type ligand

Anionic [Pd(0)−X]− ate complex were proposed as key intermediates in Pd-catalyzed cross-coupling for decades, but their isolation remained elusive. Herein, a chelating Lewis acidic bis(amidophenolato)silane is introduced as a strong Z-type ligand which enables the characterization of the first anion...

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Main Authors: Ansmann, Nils (Author) , Münch, Joshua (Author) , Schorpp, Marcel (Author) , Greb, Lutz (Author)
Format: Article (Journal)
Language:English
Published: 6 December 2023
In: Angewandte Chemie. International edition
Year: 2023, Volume: 62, Issue: 50, Pages: 1-6
ISSN:1521-3773
DOI:10.1002/anie.202313636
Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/anie.202313636
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202313636
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Author Notes:Nils Ansmann, Joshua Münch, Marcel Schorpp, and Lutz Greb

MARC

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