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Stabilization of acenes: 'Geländer'-pentacenes

We report soluble tetrakis-biphenyl substituted pentacenes comprised of sp2 carbons and synthesized from pentacene-5,7,12,14-tetraone. Intramolecular Yamamoto coupling of two tetrakis(chlorobiphenylyl)pentacenes yields helical, doubly wrapped pentacenes, in which the quaterphenylene units solubilize...

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Main Authors: Ludwig, Philipp (Author) , Rominger, Frank (Author) , Freudenberg, Jan (Author) , Bunz, Uwe H. F. (Author)
Format: Article (Journal)
Language:English
Published: 05 January 2024
In: Angewandte Chemie. International edition
Year: 2024, Volume: 63, Issue: 13, Pages: 1-5
ISSN:1521-3773
DOI:10.1002/anie.202316902
Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/anie.202316902
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202316902
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Author Notes:Philipp Ludwig, Frank Rominger, Jan Freudenberg and Uwe H.F. Bunz

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