Synthesis of chiral pyrene-based 1,4-dithiins
The 1,4-dithiin motif is known for its reversible redox properties to generate radical cations and diradical dications and thus is interesting for organic electronic applications. However, examples where this motif is embedded into chiral larger fused aromatic compounds are very rare. Here we descri...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
05 January 2024
|
| In: |
Angewandte Chemie. International edition
Year: 2024, Volume: 63, Issue: 11, Pages: 1-12 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.202319389 |
| Online Access: | Resolving-System, kostenfrei, Volltext: https://doi.org/10.1002/anie.202319389 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202319389 
|
| Author Notes: | Christoph Keck, Frank Rominger, and Michael Mastalerz |
MARC
| LEADER | 00000caa a22000002c 4500 | ||
|---|---|---|---|
| 001 | 1881562077 | ||
| 003 | DE-627 | ||
| 005 | 20240725161847.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 240226s2024 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/anie.202319389 |2 doi | |
| 035 | |a (DE-627)1881562077 | ||
| 035 | |a (DE-599)KXP1881562077 | ||
| 035 | |a (OCoLC)1425200144 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Keck, Christoph |e VerfasserIn |0 (DE-588)1321667892 |0 (DE-627)1881557650 |4 aut | |
| 245 | 1 | 0 | |a Synthesis of chiral pyrene-based 1,4-dithiins |c Christoph Keck, Frank Rominger, and Michael Mastalerz |
| 264 | 1 | |c 05 January 2024 | |
| 300 | |a 12 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 26.02.2024 | ||
| 520 | |a The 1,4-dithiin motif is known for its reversible redox properties to generate radical cations and diradical dications and thus is interesting for organic electronic applications. However, examples where this motif is embedded into chiral larger fused aromatic compounds are very rare. Here we describe the syntheses of several structurally related pyrene fused dithiins and their spectroscopic investigations with a focus on tuning circular dichroism, with respect to the g values, depending on their connectivity. | ||
| 650 | 4 | |a 1 | |
| 650 | 4 | |a 4-Dithiin | |
| 650 | 4 | |a Absorption Spectroscopy | |
| 650 | 4 | |a Chirality | |
| 650 | 4 | |a Circular Dichroism | |
| 650 | 4 | |a Pyrene | |
| 700 | 1 | |a Rominger, Frank |d 1964- |e VerfasserIn |0 (DE-588)1019978228 |0 (DE-627)691067821 |0 (DE-576)359202756 |4 aut | |
| 700 | 1 | |a Mastalerz, Michael |d 1972- |e VerfasserIn |0 (DE-588)130559431 |0 (DE-627)503822701 |0 (DE-576)298267950 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Angewandte Chemie. International edition |d Weinheim : Wiley-VCH, 1998 |g 63(2024), 11, Artikel-ID e202319389, Seite 1-12 |h Online-Ressource |w (DE-627)320497879 |w (DE-600)2011836-3 |w (DE-576)111552060 |x 1521-3773 |7 nnas |a Synthesis of chiral pyrene-based 1,4-dithiins |
| 773 | 1 | 8 | |g volume:63 |g year:2024 |g number:11 |g elocationid:e202319389 |g pages:1-12 |g extent:12 |a Synthesis of chiral pyrene-based 1,4-dithiins |
| 787 | 0 | 8 | |i Forschungsdaten |a Keck, Christoph |t Synthesis of chiral pyrene-based 1,4-dithiins [data] |d Heidelberg : Universität, 2024 |h 1 Online-Ressource (4 Files) |w (DE-627)1881555976 |
| 856 | 4 | 0 | |u https://doi.org/10.1002/anie.202319389 |x Resolving-System |x Verlag |z kostenfrei |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202319389 |x Verlag |z kostenfrei |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20240226 | ||
| 993 | |a Article | ||
| 994 | |a 2024 | ||
| 998 | |g 130559431 |a Mastalerz, Michael |m 130559431:Mastalerz, Michael |d 120000 |d 120100 |e 120000PM130559431 |e 120100PM130559431 |k 0/120000/ |k 1/120000/120100/ |p 3 |y j | ||
| 998 | |g 1019978228 |a Rominger, Frank |m 1019978228:Rominger, Frank |d 120000 |d 120100 |e 120000PR1019978228 |e 120100PR1019978228 |k 0/120000/ |k 1/120000/120100/ |p 2 | ||
| 999 | |a KXP-PPN1881562077 |e 4491068399 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"title":[{"title_sort":"Synthesis of chiral pyrene-based 1,4-dithiins","title":"Synthesis of chiral pyrene-based 1,4-dithiins"}],"language":["eng"],"physDesc":[{"extent":"12 S."}],"name":{"displayForm":["Christoph Keck, Frank Rominger, and Michael Mastalerz"]},"note":["Gesehen am 26.02.2024"],"type":{"bibl":"article-journal","media":"Online-Ressource"},"person":[{"given":"Christoph","family":"Keck","display":"Keck, Christoph","role":"aut"},{"given":"Frank","display":"Rominger, Frank","family":"Rominger","role":"aut"},{"family":"Mastalerz","display":"Mastalerz, Michael","role":"aut","given":"Michael"}],"relHost":[{"type":{"media":"Online-Ressource","bibl":"periodical"},"titleAlt":[{"title":"Angewandte Chemie / International edition"}],"recId":"320497879","part":{"text":"63(2024), 11, Artikel-ID e202319389, Seite 1-12","year":"2024","extent":"12","issue":"11","pages":"1-12","volume":"63"},"disp":"Synthesis of chiral pyrene-based 1,4-dithiinsAngewandte Chemie. International edition","corporate":[{"role":"isb","display":"Gesellschaft Deutscher Chemiker"}],"pubHistory":["37.1998 -"],"id":{"eki":["320497879"],"zdb":["2011836-3"],"doi":["10.1002/(ISSN)1521-3773"],"issn":["1521-3773"]},"origin":[{"publisher":"Wiley-VCH","publisherPlace":"Weinheim","dateIssuedKey":"1998","dateIssuedDisp":"1998-"}],"note":["Gesehen am 20.12.2022","Fortsetzung der Druck-Ausgabe"],"language":["eng"],"physDesc":[{"extent":"Online-Ressource"}],"title":[{"title":"Angewandte Chemie","subtitle":"a journal of the Gesellschaft Deutscher Chemiker","title_sort":"Angewandte Chemie","partname":"International edition"}]}],"recId":"1881562077","id":{"eki":["1881562077"],"doi":["10.1002/anie.202319389"]},"origin":[{"dateIssuedDisp":"05 January 2024","dateIssuedKey":"2024"}]} | ||
| SRT | |a KECKCHRISTSYNTHESISO0520 | ||