Halogenated phenazinothiadiazoles: electron transporting materials [data]
Triisopropylsilyl-(TIPS)-alkynylated phenazinothiadiazoles were prepared by the condensation of halogenated ortho-quinones and TIPS-alkynylated 5,6-diamino-2,1,3-benzothiadiazole with different combinations of halogen substituents. The compounds pack in brickwall motif of head-to-head dimers featuri...
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| Hauptverfasser: | , , , , , , , |
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| Dokumenttyp: | Datenbank Forschungsdaten |
| Sprache: | Englisch |
| Veröffentlicht: |
Heidelberg
Universität
2024-01-08
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| DOI: | 10.11588/data/PKX5CI |
| Schlagworte: | |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.11588/data/PKX5CI Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/PKX5CI 
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| Verfasserangaben: | Wansheng Zong, Nikolai Hippchen, Benedikt Dittmar, Maximilian Elter, Philipp Ludwig, Frank Rominger, Jan Freudenberg, Uwe H.F. Bunz |
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| 520 | |a Triisopropylsilyl-(TIPS)-alkynylated phenazinothiadiazoles were prepared by the condensation of halogenated ortho-quinones and TIPS-alkynylated 5,6-diamino-2,1,3-benzothiadiazole with different combinations of halogen substituents. The compounds pack in brickwall motif of head-to-head dimers featuring intermolecular S-N contacts and short π-π distances, suggesting their suitability as n-channel materials in organic thin film transistors. The halogenated phenazinothiadiazoles show electron mobilities μmax ranging between 0.14 cm2V-1 s-1 and 0.76 cm2 V-1 s-1. | ||
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