Designing structurally ordered Pt/Sn nanoparticles in ionic liquids and their enhanced catalytic performance
Multimetallic nanoparticles (NPs) often exhibit enhanced catalytic properties that differ from their parent materials. Carefully exploring the structures of multimetallic NPs is a prerequisite for understanding the structure- and composition-associated properties. Herein, intermetallic Pt/Sn NPs wit...
Gespeichert in:
| Hauptverfasser: | , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
December 2020
|
| In: |
ChemNanoMat
Year: 2020, Jahrgang: 6, Heft: 12, Pages: 1854-1862 |
| ISSN: | 2199-692X |
| DOI: | 10.1002/cnma.202000433 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/cnma.202000433 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/cnma.202000433 
|
| Verfasserangaben: | Christine Dietrich, Martin Hähsler, Wu Wang, Christian Kübel, and Silke Behrens |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1886089701 | ||
| 003 | DE-627 | ||
| 005 | 20250116223559.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 240417s2020 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/cnma.202000433 |2 doi | |
| 035 | |a (DE-627)1886089701 | ||
| 035 | |a (DE-599)KXP1886089701 | ||
| 035 | |a (OCoLC)1443668833 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Dietrich, Christine |e VerfasserIn |0 (DE-588)1171496613 |0 (DE-627)1040565743 |0 (DE-576)513764631 |4 aut | |
| 245 | 1 | 0 | |a Designing structurally ordered Pt/Sn nanoparticles in ionic liquids and their enhanced catalytic performance |c Christine Dietrich, Martin Hähsler, Wu Wang, Christian Kübel, and Silke Behrens |
| 264 | 1 | |c December 2020 | |
| 300 | |b Illustrationen | ||
| 300 | |a 9 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Online veröffentlicht: 21. Oktober 2020 | ||
| 500 | |a Gesehen am 17.04.2024 | ||
| 520 | |a Multimetallic nanoparticles (NPs) often exhibit enhanced catalytic properties that differ from their parent materials. Carefully exploring the structures of multimetallic NPs is a prerequisite for understanding the structure- and composition-associated properties. Herein, intermetallic Pt/Sn NPs with tunable compositions are designed exploiting the beneficial properties of ionic liquids (ILs) in a one-pot synthetic procedure. Metal salt precursors are reduced with triethylhydridoborate, whereby the cation of the triethylhydridoborate is adapted to the cation of the IL. Both the initial metal precursor ratio and the type of IL influence the structure of the NPs, with the effect of the IL being more pronounced. PtSn nanocrystals are obtained as phase pure products under optimized reaction conditions, whereby a microwave-assisted approach leads to higher crystallinity. In the hydrogenation of α,β-unsaturated aldehydes, the catalytic performance obviously depend on the NP composition. In bimetallic Pt/Sn NPs, higher Pt content leads to increased conversion, while increase in Sn increases selectivity to the cinnamic alcohol. | ||
| 650 | 4 | |a Intermetallic nanoparticles | |
| 650 | 4 | |a ionic liquids | |
| 650 | 4 | |a Pt/Sn | |
| 650 | 4 | |a selective hydrogenation | |
| 650 | 4 | |a α | |
| 650 | 4 | |a β-unsaturated aldehydes | |
| 700 | 1 | |a Hähsler, Martin |d 1986- |e VerfasserIn |0 (DE-588)1207115401 |0 (DE-627)1693375419 |4 aut | |
| 700 | 1 | |8 1\p |a Wang, Wu |e VerfasserIn |0 (DE-588)1333669437 |0 (DE-627)1891997637 |4 aut | |
| 700 | 1 | |8 2\p |a Kübel, Christian |d 1971- |e VerfasserIn |0 (DE-588)120884399 |0 (DE-627)705062244 |0 (DE-576)292430620 |4 aut | |
| 700 | 1 | |a Behrens, Silke |d 1969- |e VerfasserIn |0 (DE-588)120297752 |0 (DE-627)696543656 |0 (DE-576)292145772 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t ChemNanoMat |d Weinheim : Wiley, 2015 |g 6(2020), 12 vom: Dez., Seite 1854-1862 |h Online-Ressource |w (DE-627)830136177 |w (DE-600)2827071-X |w (DE-576)434943770 |x 2199-692X |7 nnas |a Designing structurally ordered Pt/Sn nanoparticles in ionic liquids and their enhanced catalytic performance |
| 773 | 1 | 8 | |g volume:6 |g year:2020 |g number:12 |g month:12 |g pages:1854-1862 |g extent:9 |a Designing structurally ordered Pt/Sn nanoparticles in ionic liquids and their enhanced catalytic performance |
| 856 | 4 | 0 | |u https://doi.org/10.1002/cnma.202000433 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/cnma.202000433 |x Verlag |z lizenzpflichtig |3 Volltext |
| 883 | |8 1\p |a cgwrk |d 20241001 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | ||
| 883 | |8 2\p |a cgwrk |d 20241001 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | ||
| 951 | |a AR | ||
| 992 | |a 20240417 | ||
| 993 | |a Article | ||
| 994 | |a 2020 | ||
| 998 | |g 120297752 |a Behrens, Silke |m 120297752:Behrens, Silke |d 120000 |e 120000PB120297752 |k 0/120000/ |p 5 |y j | ||
| 998 | |g 1207115401 |a Hähsler, Martin |m 1207115401:Hähsler, Martin |d 120000 |e 120000PH1207115401 |k 0/120000/ |p 2 | ||
| 998 | |g 1171496613 |a Dietrich, Christine |m 1171496613:Dietrich, Christine |p 1 |x j | ||
| 999 | |a KXP-PPN1886089701 |e 4512984739 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"language":["eng"],"name":{"displayForm":["Christine Dietrich, Martin Hähsler, Wu Wang, Christian Kübel, and Silke Behrens"]},"title":[{"title":"Designing structurally ordered Pt/Sn nanoparticles in ionic liquids and their enhanced catalytic performance","title_sort":"Designing structurally ordered Pt/Sn nanoparticles in ionic liquids and their enhanced catalytic performance"}],"note":["Online veröffentlicht: 21. Oktober 2020","Gesehen am 17.04.2024"],"id":{"doi":["10.1002/cnma.202000433"],"eki":["1886089701"]},"person":[{"role":"aut","roleDisplay":"VerfasserIn","display":"Dietrich, Christine","family":"Dietrich","given":"Christine"},{"family":"Hähsler","display":"Hähsler, Martin","role":"aut","roleDisplay":"VerfasserIn","given":"Martin"},{"role":"aut","roleDisplay":"VerfasserIn","family":"Wang","display":"Wang, Wu","given":"Wu"},{"given":"Christian","display":"Kübel, Christian","family":"Kübel","roleDisplay":"VerfasserIn","role":"aut"},{"given":"Silke","family":"Behrens","display":"Behrens, Silke","role":"aut","roleDisplay":"VerfasserIn"}],"relHost":[{"part":{"volume":"6","pages":"1854-1862","extent":"9","text":"6(2020), 12 vom: Dez., Seite 1854-1862","issue":"12","year":"2020"},"pubHistory":["1.2015 -"],"type":{"media":"Online-Ressource","bibl":"periodical"},"origin":[{"dateIssuedDisp":"[2015]-","publisher":"Wiley","publisherPlace":"Weinheim"}],"physDesc":[{"extent":"Online-Ressource"}],"recId":"830136177","id":{"issn":["2199-692X"],"doi":["10.1002/(ISSN)2199-692X"],"zdb":["2827071-X"],"eki":["830136177"]},"note":["Gesehen am 14.10.2022"],"title":[{"title_sort":"ChemNanoMat","title":"ChemNanoMat","subtitle":"Chemistry of Nanomaterials for Energy, Biology and More"}],"language":["eng"],"disp":"Designing structurally ordered Pt/Sn nanoparticles in ionic liquids and their enhanced catalytic performanceChemNanoMat"}],"recId":"1886089701","physDesc":[{"noteIll":"Illustrationen","extent":"9 S."}],"origin":[{"dateIssuedKey":"2020","dateIssuedDisp":"December 2020"}],"type":{"bibl":"article-journal","media":"Online-Ressource"}} | ||
| SRT | |a DIETRICHCHDESIGNINGS2020 | ||