Spectroscopic study on the complexation of trivalent actinide and lanthanide ions with TEDGA in solution
NMR spectroscopy studies on the complexation of La(III), Sm(III), Lu(III), Y(III) and Am(III) with N,N,N′,N′-tetraethyldiglycolamide (TEDGA) have been performed. Initial studies concerning the stoichiometry of the complexes prove the formation of [M(TEDGA)3]3+ in D2O and [M(TEDGA)1-3]3+ in CD3CN. De...
Gespeichert in:
| Hauptverfasser: | , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
April 2, 2024
|
| In: |
European journal of inorganic chemistry
Year: 2024, Jahrgang: 27, Heft: 10, Pages: 1-8 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.202300720 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/ejic.202300720 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.202300720 
|
| Verfasserangaben: | Thomas Sittel, Maximilian Meißner, Max Keller, Andreas Geist, and Petra J. Panak |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1890976679 | ||
| 003 | DE-627 | ||
| 005 | 20250117011040.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 240610s2024 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/ejic.202300720 |2 doi | |
| 035 | |a (DE-627)1890976679 | ||
| 035 | |a (DE-599)KXP1890976679 | ||
| 035 | |a (OCoLC)1475288018 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Sittel, Thomas |d 1992- |e VerfasserIn |0 (DE-588)1236244672 |0 (DE-627)1761476300 |4 aut | |
| 245 | 1 | 0 | |a Spectroscopic study on the complexation of trivalent actinide and lanthanide ions with TEDGA in solution |c Thomas Sittel, Maximilian Meißner, Max Keller, Andreas Geist, and Petra J. Panak |
| 264 | 1 | |c April 2, 2024 | |
| 300 | |b Illustrationen | ||
| 300 | |a 8 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Zuerst veröffentlicht: 18. Januar 2024 | ||
| 500 | |a Gesehen am 10.06.2024 | ||
| 520 | |a NMR spectroscopy studies on the complexation of La(III), Sm(III), Lu(III), Y(III) and Am(III) with N,N,N′,N′-tetraethyldiglycolamide (TEDGA) have been performed. Initial studies concerning the stoichiometry of the complexes prove the formation of [M(TEDGA)3]3+ in D2O and [M(TEDGA)1-3]3+ in CD3CN. Decreasing the solvent polarity translates to an increase of the complex stability as shown by complementary TRLFS studies with Cm(III). Due to delocalization of the lone electron pair of the amide nitrogen atom, the M(III)−O interaction has been studied indirectly by collecting 13C and 15N NMR data. The observed chemical shifts prove that the interaction of the trivalent ions, An(III) and Ln(III), and TEDGA is almost identical. | ||
| 650 | 4 | |a Actinides | |
| 650 | 4 | |a Diglycolamides | |
| 650 | 4 | |a f-elements | |
| 650 | 4 | |a Lanthanides | |
| 650 | 4 | |a Spectroscopy | |
| 700 | 1 | |a Meißner, Maximilian |e VerfasserIn |4 aut | |
| 700 | 1 | |a Keller, Max |e VerfasserIn |4 aut | |
| 700 | 1 | |8 1\p |a Geist, Andreas |e VerfasserIn |0 (DE-588)1161861556 |0 (DE-627)102538234X |0 (DE-576)506942112 |4 aut | |
| 700 | 1 | |a Panak, Petra |e VerfasserIn |0 (DE-588)1084656000 |0 (DE-627)848640217 |0 (DE-576)456626727 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t European journal of inorganic chemistry |d Weinheim : Wiley-VCH, 1998 |g 27(2024), 10 vom: Apr., Artikel-ID e202300720, Seite 1-8 |h Online-Ressource |w (DE-627)269534520 |w (DE-600)1475009-0 |w (DE-576)077884671 |x 1099-0682 |7 nnas |a Spectroscopic study on the complexation of trivalent actinide and lanthanide ions with TEDGA in solution |
| 773 | 1 | 8 | |g volume:27 |g year:2024 |g number:10 |g month:04 |g elocationid:e202300720 |g pages:1-8 |g extent:8 |a Spectroscopic study on the complexation of trivalent actinide and lanthanide ions with TEDGA in solution |
| 856 | 4 | 0 | |u https://doi.org/10.1002/ejic.202300720 |x Verlag |x Resolving-System |z kostenfrei |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.202300720 |x Verlag |z kostenfrei |3 Volltext |
| 883 | |8 1\p |a cgwrk |d 20241001 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | ||
| 951 | |a AR | ||
| 992 | |a 20240610 | ||
| 993 | |a Article | ||
| 994 | |a 2024 | ||
| 998 | |g 1084656000 |a Panak, Petra |m 1084656000:Panak, Petra |d 120000 |d 120300 |e 120000PP1084656000 |e 120300PP1084656000 |k 0/120000/ |k 1/120000/120300/ |p 5 |y j | ||
| 999 | |a KXP-PPN1890976679 |e 4536003592 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"origin":[{"dateIssuedDisp":"April 2, 2024","dateIssuedKey":"2024"}],"language":["eng"],"recId":"1890976679","relHost":[{"physDesc":[{"extent":"Online-Ressource"}],"recId":"269534520","language":["eng"],"origin":[{"publisher":"Wiley-VCH","publisherPlace":"Weinheim","dateIssuedKey":"1998","dateIssuedDisp":"1998-"}],"disp":"Spectroscopic study on the complexation of trivalent actinide and lanthanide ions with TEDGA in solutionEuropean journal of inorganic chemistry","title":[{"title_sort":"European journal of inorganic chemistry","title":"European journal of inorganic chemistry"}],"pubHistory":["Volume 1998, Issue 1 (January 1998)-"],"part":{"issue":"10","extent":"8","text":"27(2024), 10 vom: Apr., Artikel-ID e202300720, Seite 1-8","year":"2024","volume":"27","pages":"1-8"},"type":{"bibl":"periodical","media":"Online-Ressource"},"id":{"doi":["10.1002/(ISSN)1099-0682c"],"zdb":["1475009-0"],"issn":["1099-0682"],"eki":["269534520"]},"note":["Gesehen am 27.02.24","Fortsetzung der Druck-Ausgabe"]}],"title":[{"title":"Spectroscopic study on the complexation of trivalent actinide and lanthanide ions with TEDGA in solution","title_sort":"Spectroscopic study on the complexation of trivalent actinide and lanthanide ions with TEDGA in solution"}],"person":[{"given":"Thomas","family":"Sittel","roleDisplay":"VerfasserIn","display":"Sittel, Thomas","role":"aut"},{"roleDisplay":"VerfasserIn","given":"Maximilian","family":"Meißner","role":"aut","display":"Meißner, Maximilian"},{"role":"aut","display":"Keller, Max","roleDisplay":"VerfasserIn","family":"Keller","given":"Max"},{"roleDisplay":"VerfasserIn","given":"Andreas","family":"Geist","role":"aut","display":"Geist, Andreas"},{"roleDisplay":"VerfasserIn","family":"Panak","given":"Petra","role":"aut","display":"Panak, Petra"}],"physDesc":[{"extent":"8 S.","noteIll":"Illustrationen"}],"note":["Zuerst veröffentlicht: 18. Januar 2024","Gesehen am 10.06.2024"],"name":{"displayForm":["Thomas Sittel, Maximilian Meißner, Max Keller, Andreas Geist, and Petra J. Panak"]},"id":{"doi":["10.1002/ejic.202300720"],"eki":["1890976679"]},"type":{"media":"Online-Ressource","bibl":"article-journal"}} | ||
| SRT | |a SITTELTHOMSPECTROSCO2202 | ||