Synthesis of N-thioacetyl gangliosides GM1 and GM3
Reaction of de-N-acetyl gangliosides GM1 (1) and GM3 (2b) with methyl dithioacetate (3) afforded N-thioacetyl GM1 (1c) and N-thioacetyl GM3 (2c) with the oxygen of the acetamido group of N-acetylneuraminic acid residue replaced by sulfur.
Gespeichert in:
| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
7 December 1995
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| In: |
Bioorganic & medicinal chemistry letters
Year: 1995, Jahrgang: 5, Heft: 23, Pages: 2805-2808 |
| ISSN: | 1464-3405 |
| DOI: | 10.1016/0960-894X(95)00490-K |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/0960-894X(95)00490-K Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/0960894X9500490K 
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| Verfasserangaben: | Rainer Isecke, Reinhard Brossmer, Sandro Sonnino |
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| 520 | |a Reaction of de-N-acetyl gangliosides GM1 (1) and GM3 (2b) with methyl dithioacetate (3) afforded N-thioacetyl GM1 (1c) and N-thioacetyl GM3 (2c) with the oxygen of the acetamido group of N-acetylneuraminic acid residue replaced by sulfur. | ||
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