Supramolecular trapping of a cationic all-metal σ-aromatic {Bi4} ring
Aromaticity in organic molecules is well defined, but its role in metal-only rings remains controversial. Here we introduce a supramolecular stabilization approach of a cationic {Bi4} rhomboid within the symmetric charge sphere of two bowl-shaped dianionic calix[4]pyrrolato indinates. Crystallograph...
Gespeichert in:
| Hauptverfasser: | , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
17 May 2024
|
| In: |
Nature chemistry
Year: 2024, Pages: 1-8 |
| ISSN: | 1755-4349 |
| DOI: | 10.1038/s41557-024-01530-z |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1038/s41557-024-01530-z Verlag, lizenzpflichtig, Volltext: https://www.nature.com/articles/s41557-024-01530-z 
|
| Verfasserangaben: | Ravi Yadav, Avijit Maiti, Marcel Schorpp, Jürgen Graf, Florian Weigend, Lutz Greb |
MARC
| LEADER | 00000caa a22000002c 4500 | ||
|---|---|---|---|
| 001 | 1892776391 | ||
| 003 | DE-627 | ||
| 005 | 20241205145358.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 240701s2024 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1038/s41557-024-01530-z |2 doi | |
| 035 | |a (DE-627)1892776391 | ||
| 035 | |a (DE-599)KXP1892776391 | ||
| 035 | |a (OCoLC)1475301027 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Yadav, Ravi |d 1993- |e VerfasserIn |0 (DE-588)1201321506 |0 (DE-627)1684864402 |4 aut | |
| 245 | 1 | 0 | |a Supramolecular trapping of a cationic all-metal σ-aromatic {Bi4} ring |c Ravi Yadav, Avijit Maiti, Marcel Schorpp, Jürgen Graf, Florian Weigend, Lutz Greb |
| 246 | 3 | 3 | |a Supramolecular trapping of a cationic all-metal delta-aromatic {Bi 4} ring |
| 264 | 1 | |c 17 May 2024 | |
| 300 | |a 8 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Im Titel ist die Zahl "4" tiefgestellt | ||
| 500 | |a Gesehen am 01.07.2024 | ||
| 520 | |a Aromaticity in organic molecules is well defined, but its role in metal-only rings remains controversial. Here we introduce a supramolecular stabilization approach of a cationic {Bi4} rhomboid within the symmetric charge sphere of two bowl-shaped dianionic calix[4]pyrrolato indinates. Crystallographic and spectroscopic characterization, quantum chemical analysis and magnetically induced ring currents indicate σ-aromaticity in the formally tetracationic 16-valence electron [Bi4]4+ ring. Computational screening for other p-block elements identifies the planar rhomboid as the globally preferred structure for 16-valence electron four-atomic clusters. The aromatic [Bi4]4+ is isoelectronic to the [Al4]4−, a motif previously observed as antiaromatic in Li3[Al4]− in the gas phase. Thus, subtle factors such as charge isotropy seem to decide over aromaticity or antiaromaticity, advising for caution in debates based on the Hückel model—a concept valid for second-row elements but less deterministic for the heavier congeners. | ||
| 650 | 4 | |a Chemical bonding | |
| 650 | 4 | |a Molecular capsules | |
| 650 | 4 | |a Organometallic chemistry | |
| 700 | 1 | |a Maiti, Avijit |e VerfasserIn |0 (DE-588)1334511950 |0 (DE-627)1892777487 |4 aut | |
| 700 | 1 | |a Schorpp, Marcel |e VerfasserIn |4 aut | |
| 700 | 1 | |a Graf, Jürgen |d 1975- |e VerfasserIn |0 (DE-588)132485699 |0 (DE-627)522960065 |0 (DE-576)299176142 |4 aut | |
| 700 | 1 | |a Weigend, Florian |e VerfasserIn |4 aut | |
| 700 | 1 | |a Greb, Lutz |e VerfasserIn |0 (DE-588)1043619879 |0 (DE-627)770726526 |0 (DE-576)395158265 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Nature chemistry |d London : Nature Publishing Group, 2009 |g (2024), Seite 1-8 |h Online-Ressource |w (DE-627)58474370X |w (DE-600)2464596-5 |w (DE-576)290238226 |x 1755-4349 |7 nnas |a Supramolecular trapping of a cationic all-metal σ-aromatic {Bi4} ring |
| 773 | 1 | 8 | |g year:2024 |g pages:1-8 |g extent:8 |a Supramolecular trapping of a cationic all-metal σ-aromatic {Bi4} ring |
| 856 | 4 | 0 | |u https://doi.org/10.1038/s41557-024-01530-z |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://www.nature.com/articles/s41557-024-01530-z |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20240701 | ||
| 994 | |a 2024 | ||
| 998 | |g 1043619879 |a Greb, Lutz |m 1043619879:Greb, Lutz |d 120000 |d 120200 |e 120000PG1043619879 |e 120200PG1043619879 |k 0/120000/ |k 1/120000/120200/ |p 6 |y j | ||
| 998 | |g 132485699 |a Graf, Jürgen |m 132485699:Graf, Jürgen |d 120000 |d 120100 |e 120000PG132485699 |e 120100PG132485699 |k 0/120000/ |k 1/120000/120100/ |p 4 | ||
| 998 | |g 1334511950 |a Maiti, Avijit |m 1334511950:Maiti, Avijit |d 120000 |d 120200 |e 120000PM1334511950 |e 120200PM1334511950 |k 0/120000/ |k 1/120000/120200/ |p 2 | ||
| 999 | |a KXP-PPN1892776391 |e 4544565650 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"titleAlt":[{"title":"Supramolecular trapping of a cationic all-metal delta-aromatic {Bi 4} ring"}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"relHost":[{"recId":"58474370X","physDesc":[{"extent":"Online-Ressource"}],"note":["Gesehen am 30.08.10"],"type":{"bibl":"periodical","media":"Online-Ressource"},"pubHistory":["1.2009 -"],"language":["eng"],"origin":[{"dateIssuedKey":"2009","publisherPlace":"London","publisher":"Nature Publishing Group","dateIssuedDisp":"2009-"}],"id":{"zdb":["2464596-5"],"issn":["1755-4349"],"eki":["58474370X"]},"part":{"pages":"1-8","extent":"8","text":"(2024), Seite 1-8","year":"2024"},"title":[{"title_sort":"Nature chemistry","title":"Nature chemistry"}],"disp":"Supramolecular trapping of a cationic all-metal σ-aromatic {Bi4} ringNature chemistry"}],"recId":"1892776391","physDesc":[{"extent":"8 S."}],"note":["Im Titel ist die Zahl \"4\" tiefgestellt","Gesehen am 01.07.2024"],"origin":[{"dateIssuedDisp":"17 May 2024","dateIssuedKey":"2024"}],"person":[{"given":"Ravi","family":"Yadav","display":"Yadav, Ravi","role":"aut"},{"given":"Avijit","role":"aut","display":"Maiti, Avijit","family":"Maiti"},{"given":"Marcel","family":"Schorpp","display":"Schorpp, Marcel","role":"aut"},{"given":"Jürgen","role":"aut","display":"Graf, Jürgen","family":"Graf"},{"given":"Florian","role":"aut","display":"Weigend, Florian","family":"Weigend"},{"role":"aut","display":"Greb, Lutz","family":"Greb","given":"Lutz"}],"id":{"eki":["1892776391"],"doi":["10.1038/s41557-024-01530-z"]},"name":{"displayForm":["Ravi Yadav, Avijit Maiti, Marcel Schorpp, Jürgen Graf, Florian Weigend, Lutz Greb"]},"title":[{"title":"Supramolecular trapping of a cationic all-metal σ-aromatic {Bi4} ring","title_sort":"Supramolecular trapping of a cationic all-metal σ-aromatic {Bi4} ring"}],"language":["eng"]} | ||
| SRT | |a YADAVRAVIMSUPRAMOLEC1720 | ||