Chrysene-based blue emitters
Chrysene and its bisbenzannulated homologue, naphtho[2,3-c]tetraphene, were synthesized through a PtCl2-catalyzed cyclization of alkynes, which also furnished corresponding biaryls subsequent to a Glaser coupling reaction of the starting alkynes. The optoelectronic properties of 5,5′-bichrysenyl and...
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| Main Authors: | , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
2020
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| In: |
Chemistry - a European journal
Year: 2020, Volume: 26, Issue: 66, Pages: 15089-15093 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.202001808 |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/chem.202001808 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202001808 |
| Author Notes: | Marvin Nathusius, Barbara Ejlli, Frank Rominger, Jan Freudenberg, Uwe H.F. Bunz, and Klaus Müllen |
MARC
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| 520 | |a Chrysene and its bisbenzannulated homologue, naphtho[2,3-c]tetraphene, were synthesized through a PtCl2-catalyzed cyclization of alkynes, which also furnished corresponding biaryls subsequent to a Glaser coupling reaction of the starting alkynes. The optoelectronic properties of 5,5′-bichrysenyl and 6,6′-binaphtho[2,3-c]tetraphene were compared to their chrysene-based “monomers”. Oxidative cyclodehydrogenations of bichrysenyl and its higher homologue towards large nanographenes were also investigated. | ||
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| 650 | 4 | |a solubility increase | |
| 650 | 4 | |a twisted biaryls | |
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