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Azaacene diradicals based on Non-Kekulé meta-quinodimethane with large two-photon cross-sections in the infrared spectral region

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Non-Kekulé quinoidal azaacences m-A (1a,b) were synthesized and compared to their para- and ortho-quinodimethane analogues. m-Adisplay high diradical characters (1b: y0 = 0.88) due to their meta-quinodimethane (m-QDM) topology. Electron paramagnetic, nuclear magnetic resonance spectroscopies and su...

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Main Authors: Fuchs, Kathleen (Author) , Oberhof, Nils (Author) , Sauter, Gabriel (Author) , Pollien, Audrey (Author) , Brödner, Kerstin (Author) , Rominger, Frank (Author) , Freudenberg, Jan (Author) , Dreuw, Andreas (Author) , Tegeder, Petra (Author) , Bunz, Uwe H. F. (Author)
Format: Article (Journal)
Language:English
Published: 27 August 2024
In: Angewandte Chemie. International edition
Year: 2024, Pages: 1-9
ISSN:1521-3773
DOI:10.1002/anie.202406384
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.202406384
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202406384
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Author Notes:Kathleen Fuchs, Nils Oberhof, Gabriel Sauter, Audrey Pollien, Kerstin Brödner, Frank Rominger, Jan Freudenberg, Andreas Dreuw, Petra Tegeder, and Uwe Heiko Bunz
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Azaacene diradicals based on non-kekulé meta-quinodimethane with large two-photon cross-sections in the infrared spectral region by Fuchs, Kathleen (Author) , Oberhof, Nils (Author) , Sauter, Gabriel (Author) , Pollien, Audrey (Author) , Brödner, Kerstin (Author) , Rominger, Frank (Author) , Freudenberg, Jan (Author) , Dreuw, Andreas (Author) , Tegeder, Petra (Author) , Bunz, Uwe H. F. (Author) ,


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