Phenylseleninate-connected telluroxane clusters
Hydrolysis of PhTeI3 in the presence of sodium phenylseleninate and M3+ ions (M = Y, Nd, Ce) gives well-defined, bowl-shaped telluroxane clusters. Each of the two half-spheres of the compositions [(PhTe)18{ML}O24]7+/8+ ({ML} = {Y(NO3)(H2O)}2+ (1), {Nd(NO3)(H2O)2+} (2), or {Ce(NO3)2}+ (3)) are connec...
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| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
9 September 2024
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| In: |
Inorganic chemistry
Year: 2024, Jahrgang: 63, Heft: 36, Pages: 16590-16594 |
| ISSN: | 1520-510X |
| DOI: | 10.1021/acs.inorgchem.4c02274 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1021/acs.inorgchem.4c02274
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| Verfasserangaben: | Jéssica F. Rodrigues, Ana Júlia Z. Londero, Bárbara Tirloni, Maximilian Roca Jungfer, Ulrich Abram, and Ernesto S. Lang |
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| 520 | |a Hydrolysis of PhTeI3 in the presence of sodium phenylseleninate and M3+ ions (M = Y, Nd, Ce) gives well-defined, bowl-shaped telluroxane clusters. Each of the two half-spheres of the compositions [(PhTe)18{ML}O24]7+/8+ ({ML} = {Y(NO3)(H2O)}2+ (1), {Nd(NO3)(H2O)2+} (2), or {Ce(NO3)2}+ (3)) are connected by two (compound 3) or four (compounds 1 and 2) PhSeO2– bridges. The resulting chalcogenoxane spheres have internal volumes of approximately 1500 Å3. Charge compensation is provided by nitrate ions and/or [Na2(NO3)8]6– clusters, which are located inside and surrounding these spheres. | ||
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| 700 | 1 | |a Abram, Ulrich |e VerfasserIn |4 aut | |
| 700 | 1 | |a Lang, Ernesto S. |e VerfasserIn |4 aut | |
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