Structural and electronic impacts of the axialsSubstitution at the phosphorus center of C(sp3)-bridged P-heterotriangulenes
The structural and electronic properties of the dimethylmethylene-bridged P-heterotriangulene have been systematically modulated by functionalization of its phosphorus center. The optoelectronic properties of the obtained derivatives in solution were characterized by UV/Vis absorption and emission s...
Gespeichert in:
| Hauptverfasser: | , , , , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
July 8, 2024
|
| In: |
European journal of organic chemistry
Year: 2024, Jahrgang: 27, Heft: 26, Pages: 1-6 |
| ISSN: | 1099-0690 |
| DOI: | 10.1002/ejoc.202400368 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/ejoc.202400368 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.202400368 
|
| Verfasserangaben: | Siegfried Harrer, Johannes D.R. Schühle, Christian Neiß, Marina Günthert, Lena Mittmann, Andrea Reule, Jonas Leitner, Frank Rominger, Andreas Görling, and Milan Kivala |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1905507933 | ||
| 003 | DE-627 | ||
| 005 | 20241205180652.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 241011s2024 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/ejoc.202400368 |2 doi | |
| 035 | |a (DE-627)1905507933 | ||
| 035 | |a (DE-599)KXP1905507933 | ||
| 035 | |a (OCoLC)1475315132 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Harrer, Siegfried |d 1995- |e VerfasserIn |0 (DE-588)1328901890 |0 (DE-627)1888249153 |4 aut | |
| 245 | 1 | 0 | |a Structural and electronic impacts of the axialsSubstitution at the phosphorus center of C(sp3)-bridged P-heterotriangulenes |c Siegfried Harrer, Johannes D.R. Schühle, Christian Neiß, Marina Günthert, Lena Mittmann, Andrea Reule, Jonas Leitner, Frank Rominger, Andreas Görling, and Milan Kivala |
| 264 | 1 | |c July 8, 2024 | |
| 300 | |b Illustrationen | ||
| 300 | |a 6 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 11.10.2024 | ||
| 520 | |a The structural and electronic properties of the dimethylmethylene-bridged P-heterotriangulene have been systematically modulated by functionalization of its phosphorus center. The optoelectronic properties of the obtained derivatives in solution were characterized by UV/Vis absorption and emission spectroscopy, cyclic voltammetry and 31P NMR spectroscopy. The solid state structures were analyzed by X-ray crystallography. The experimental results were corroborated by density functional theory calculations which revealed the crucial influence of the axial substitution on the bowl-shaped geometry of the phosphorus-centered polycyclic scaffold, which is proportional to the s-character of the P−X bond. The advantage of the bowl-shaped P-heterotriangulene scaffold was demonstrated by successful co-crystallization with fullerene C60. | ||
| 650 | 4 | |a bowl-shaped | |
| 650 | 4 | |a bridged triarylphosphines | |
| 650 | 4 | |a density functional theory calculations | |
| 650 | 4 | |a phosphorus heterocycles | |
| 650 | 4 | |a X-ray crystallography | |
| 700 | 1 | |a Schühle, Johannes D. R. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Neiß, Christian |e VerfasserIn |4 aut | |
| 700 | 1 | |a Günthert, Marina |e VerfasserIn |4 aut | |
| 700 | 1 | |a Mittmann, Lena |e VerfasserIn |4 aut | |
| 700 | 1 | |a Reule, Andrea |e VerfasserIn |0 (DE-588)1344647324 |0 (DE-627)1905508808 |4 aut | |
| 700 | 1 | |a Leitner, Jonas |e VerfasserIn |0 (DE-588)1278600981 |0 (DE-627)1831510251 |4 aut | |
| 700 | 1 | |a Rominger, Frank |d 1964- |e VerfasserIn |0 (DE-588)1019978228 |0 (DE-627)691067821 |0 (DE-576)359202756 |4 aut | |
| 700 | 1 | |a Görling, Andreas |e VerfasserIn |4 aut | |
| 700 | 1 | |a Kivala, Milan |e VerfasserIn |0 (DE-588)120357231X |0 (DE-627)1688558489 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t European journal of organic chemistry |d Weinheim : Wiley-VCH Verl., 1998 |g 27(2024), 26, Artikel-ID e202400368, Seite 1-6 |h Online-Ressource |w (DE-627)269534539 |w (DE-600)1475010-7 |w (DE-576)07788468X |x 1099-0690 |7 nnas |a Structural and electronic impacts of the axialsSubstitution at the phosphorus center of C(sp3)-bridged P-heterotriangulenes |
| 773 | 1 | 8 | |g volume:27 |g year:2024 |g number:26 |g elocationid:e202400368 |g pages:1-6 |g extent:6 |a Structural and electronic impacts of the axialsSubstitution at the phosphorus center of C(sp3)-bridged P-heterotriangulenes |
| 856 | 4 | 0 | |u https://doi.org/10.1002/ejoc.202400368 |x Verlag |x Resolving-System |z kostenfrei |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.202400368 |x Verlag |z kostenfrei |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20241011 | ||
| 993 | |a Article | ||
| 994 | |a 2024 | ||
| 998 | |g 120357231X |a Kivala, Milan |m 120357231X:Kivala, Milan |d 120000 |d 120100 |e 120000PK120357231X |e 120100PK120357231X |k 0/120000/ |k 1/120000/120100/ |p 10 |y j | ||
| 998 | |g 1019978228 |a Rominger, Frank |m 1019978228:Rominger, Frank |d 120000 |d 120100 |e 120000PR1019978228 |e 120100PR1019978228 |k 0/120000/ |k 1/120000/120100/ |p 8 | ||
| 998 | |g 1278600981 |a Leitner, Jonas |m 1278600981:Leitner, Jonas |d 700000 |d 708000 |e 700000PL1278600981 |e 708000PL1278600981 |k 0/700000/ |k 1/700000/708000/ |p 7 | ||
| 998 | |g 1344647324 |a Reule, Andrea |m 1344647324:Reule, Andrea |d 120000 |d 120100 |e 120000PR1344647324 |e 120100PR1344647324 |k 0/120000/ |k 1/120000/120100/ |p 6 | ||
| 998 | |g 1328901890 |a Harrer, Siegfried |m 1328901890:Harrer, Siegfried |p 1 |x j | ||
| 999 | |a KXP-PPN1905507933 |e 4592514130 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"person":[{"display":"Harrer, Siegfried","family":"Harrer","role":"aut","given":"Siegfried"},{"display":"Schühle, Johannes D. R.","family":"Schühle","given":"Johannes D. R.","role":"aut"},{"display":"Neiß, Christian","family":"Neiß","given":"Christian","role":"aut"},{"display":"Günthert, Marina","family":"Günthert","given":"Marina","role":"aut"},{"display":"Mittmann, Lena","family":"Mittmann","given":"Lena","role":"aut"},{"family":"Reule","display":"Reule, Andrea","role":"aut","given":"Andrea"},{"display":"Leitner, Jonas","family":"Leitner","given":"Jonas","role":"aut"},{"given":"Frank","role":"aut","display":"Rominger, Frank","family":"Rominger"},{"role":"aut","given":"Andreas","family":"Görling","display":"Görling, Andreas"},{"role":"aut","given":"Milan","display":"Kivala, Milan","family":"Kivala"}],"language":["eng"],"title":[{"title":"Structural and electronic impacts of the axialsSubstitution at the phosphorus center of C(sp3)-bridged P-heterotriangulenes","title_sort":"Structural and electronic impacts of the axialsSubstitution at the phosphorus center of C(sp3)-bridged P-heterotriangulenes"}],"note":["Gesehen am 11.10.2024"],"origin":[{"dateIssuedDisp":"July 8, 2024","dateIssuedKey":"2024"}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"recId":"1905507933","name":{"displayForm":["Siegfried Harrer, Johannes D.R. Schühle, Christian Neiß, Marina Günthert, Lena Mittmann, Andrea Reule, Jonas Leitner, Frank Rominger, Andreas Görling, and Milan Kivala"]},"physDesc":[{"extent":"6 S.","noteIll":"Illustrationen"}],"relHost":[{"pubHistory":["1998 -"],"recId":"269534539","physDesc":[{"extent":"Online-Ressource"}],"id":{"doi":["10.1002/(ISSN)1099-0690"],"issn":["1099-0690"],"eki":["269534539"],"zdb":["1475010-7"]},"disp":"Structural and electronic impacts of the axialsSubstitution at the phosphorus center of C(sp3)-bridged P-heterotriangulenesEuropean journal of organic chemistry","language":["eng"],"note":["Gesehen am 21.01.04"],"origin":[{"dateIssuedKey":"1998","publisher":"Wiley-VCH Verl.","dateIssuedDisp":"1998-","publisherPlace":"Weinheim"}],"title":[{"title":"European journal of organic chemistry","title_sort":"European journal of organic chemistry"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"part":{"issue":"26","extent":"6","volume":"27","year":"2024","pages":"1-6","text":"27(2024), 26, Artikel-ID e202400368, Seite 1-6"}}],"id":{"doi":["10.1002/ejoc.202400368"],"eki":["1905507933"]}} | ||
| SRT | |a HARRERSIEGSTRUCTURAL8202 | ||