Unveiling the multielectron acceptor properties of π-expanded pyracylene: reversible boat to chair conversion
In this work, the chemical reduction of a hybrid pyracylene-hexa-peri-hexabenzocoronene (HPH) nanographene was investigated with different alkali metals (Na, K, Rb) to reveal its remarkable multielectron acceptor abilities. The UV-vis and 1H NMR spectroscopy monitoring of the stepwise reduction reac...
Gespeichert in:
| Hauptverfasser: | , , , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
May 29, 2024
|
| In: |
Journal of the American Chemical Society
Year: 2024, Jahrgang: 146, Heft: 21, Pages: 14715-14723 |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/jacs.4c02314 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1021/jacs.4c02314
|
| Verfasserangaben: | Yikun Zhu, Jan Borstelmann, Oliver Bertleff, John Bergner, Zheng Wei, Christian Neiss, Andreas Görling, Milan Kivala, and Marina A. Petrukhina |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1908399309 | ||
| 003 | DE-627 | ||
| 005 | 20241205220401.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 241113s2024 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/jacs.4c02314 |2 doi | |
| 035 | |a (DE-627)1908399309 | ||
| 035 | |a (DE-599)KXP1908399309 | ||
| 035 | |a (OCoLC)1475647397 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Zhu, Yikun |e VerfasserIn |0 (DE-588)1348166665 |0 (DE-627)1908400838 |4 aut | |
| 245 | 1 | 0 | |a Unveiling the multielectron acceptor properties of π-expanded pyracylene |b reversible boat to chair conversion |c Yikun Zhu, Jan Borstelmann, Oliver Bertleff, John Bergner, Zheng Wei, Christian Neiss, Andreas Görling, Milan Kivala, and Marina A. Petrukhina |
| 264 | 1 | |c May 29, 2024 | |
| 300 | |b Illustrationen | ||
| 300 | |a 9 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 13.11.2024 | ||
| 520 | |a In this work, the chemical reduction of a hybrid pyracylene-hexa-peri-hexabenzocoronene (HPH) nanographene was investigated with different alkali metals (Na, K, Rb) to reveal its remarkable multielectron acceptor abilities. The UV-vis and 1H NMR spectroscopy monitoring of the stepwise reduction reactions supports the existence of all intermediate reduction states up to the hexaanion for HPH. Tuning the experimental conditions enabled the synthesis of the HPH anions with gradually increasing reduction states (up to −5) isolated with different alkali metal ions as crystalline materials. The single-crystal X-ray diffraction structure analysis demonstrates that the highly negatively charged HPH anions (−4 and −5) exhibit a drastic geometry change from boat-shaped (observed in the neutral parent, mono- and dianions) to a chair conformation, which was proved to be fully reversible by NMR spectroscopy. DFT calculations show that this geometry change is induced by an enhanced interaction between the coordinated metal ions and negatively charged HPH core in the chair conformation. | ||
| 700 | 1 | |a Borstelmann, Jan |d 1994- |e VerfasserIn |0 (DE-588)120355740X |0 (DE-627)1688531661 |4 aut | |
| 700 | 1 | |a Bertleff, Oliver |e VerfasserIn |4 aut | |
| 700 | 1 | |a Bergner, John |d 1995- |e VerfasserIn |0 (DE-588)1241416532 |0 (DE-627)1770926933 |4 aut | |
| 700 | 1 | |a Wei, Zheng |e VerfasserIn |4 aut | |
| 700 | 1 | |a Neiss, Christian |e VerfasserIn |4 aut | |
| 700 | 1 | |a Görling, Andreas |e VerfasserIn |4 aut | |
| 700 | 1 | |a Kivala, Milan |e VerfasserIn |4 aut | |
| 700 | 1 | |a Petrukhina, Marina A. |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |a American Chemical Society |t Journal of the American Chemical Society |d Washington, DC : ACS Publications, 1879 |g 146(2024), 21 vom: Mai, Seite 14715-14723 |w (DE-627)268132836 |w (DE-600)1472210-0 |w (DE-576)090854284 |x 1520-5126 |7 nnas |
| 773 | 1 | 8 | |g volume:146 |g year:2024 |g number:21 |g month:05 |g pages:14715-14723 |g extent:9 |a Unveiling the multielectron acceptor properties of π-expanded pyracylene reversible boat to chair conversion |
| 856 | 4 | 0 | |u https://doi.org/10.1021/jacs.4c02314 |x Verlag |x Resolving-System |z kostenfrei |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20241113 | ||
| 993 | |a Article | ||
| 994 | |a 2024 | ||
| 998 | |g 1241416532 |a Bergner, John |m 1241416532:Bergner, John |p 4 | ||
| 998 | |g 120355740X |a Borstelmann, Jan |m 120355740X:Borstelmann, Jan |d 120000 |d 120100 |e 120000PB120355740X |e 120100PB120355740X |k 0/120000/ |k 1/120000/120100/ |p 2 | ||
| 999 | |a KXP-PPN1908399309 |e 4613770084 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"origin":[{"dateIssuedKey":"2024","dateIssuedDisp":"May 29, 2024"}],"id":{"eki":["1908399309"],"doi":["10.1021/jacs.4c02314"]},"name":{"displayForm":["Yikun Zhu, Jan Borstelmann, Oliver Bertleff, John Bergner, Zheng Wei, Christian Neiss, Andreas Görling, Milan Kivala, and Marina A. Petrukhina"]},"physDesc":[{"extent":"9 S.","noteIll":"Illustrationen"}],"relHost":[{"corporate":[{"roleDisplay":"VerfasserIn","display":"American Chemical Society","role":"aut"}],"language":["eng"],"recId":"268132836","disp":"American Chemical SocietyJournal of the American Chemical Society","note":["Gesehen am 25.08.2020"],"type":{"bibl":"periodical","media":"Online-Ressource"},"titleAlt":[{"title":"JACS"},{"title":"web edition"}],"part":{"year":"2024","pages":"14715-14723","issue":"21","volume":"146","text":"146(2024), 21 vom: Mai, Seite 14715-14723","extent":"9"},"pubHistory":["1.1879 -"],"title":[{"title":"Journal of the American Chemical Society","subtitle":"JACS","title_sort":"Journal of the American Chemical Society"}],"name":{"displayForm":["Ed.: Allen J. Bard [u.a.]"]},"id":{"zdb":["1472210-0"],"eki":["268132836"],"issn":["1520-5126"]},"origin":[{"publisherPlace":"Washington, DC ; Washington, DC","publisher":"ACS Publications ; American Chemical Society","dateIssuedKey":"1879","dateIssuedDisp":"1879-"}]}],"title":[{"title_sort":"Unveiling the multielectron acceptor properties of π-expanded pyracylene","subtitle":"reversible boat to chair conversion","title":"Unveiling the multielectron acceptor properties of π-expanded pyracylene"}],"person":[{"role":"aut","display":"Zhu, Yikun","roleDisplay":"VerfasserIn","given":"Yikun","family":"Zhu"},{"given":"Jan","family":"Borstelmann","role":"aut","roleDisplay":"VerfasserIn","display":"Borstelmann, Jan"},{"family":"Bertleff","given":"Oliver","roleDisplay":"VerfasserIn","display":"Bertleff, Oliver","role":"aut"},{"family":"Bergner","given":"John","roleDisplay":"VerfasserIn","display":"Bergner, John","role":"aut"},{"family":"Wei","given":"Zheng","display":"Wei, Zheng","roleDisplay":"VerfasserIn","role":"aut"},{"given":"Christian","family":"Neiss","role":"aut","display":"Neiss, Christian","roleDisplay":"VerfasserIn"},{"display":"Görling, Andreas","roleDisplay":"VerfasserIn","role":"aut","family":"Görling","given":"Andreas"},{"role":"aut","display":"Kivala, Milan","roleDisplay":"VerfasserIn","given":"Milan","family":"Kivala"},{"given":"Marina A.","family":"Petrukhina","role":"aut","roleDisplay":"VerfasserIn","display":"Petrukhina, Marina A."}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"note":["Gesehen am 13.11.2024"],"recId":"1908399309","language":["eng"]} | ||
| SRT | |a ZHUYIKUNBOUNVEILINGT2920 | ||