Magmatic controls on volcanic sulfur emissions at the Iceland Hotspot
Outgassing of sulfur (as SO2) is one of the principal hazards posed by volcanic eruptions. However, S emission potentials of most volcanoes globally are poorly constrained due to a short observational record and an incomplete understanding of the magmatic processes that influence pre-eruptive S conc...
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| Main Authors: | , , , , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
13 May 2024
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| In: |
Geochemistry, geophysics, geosystems
Year: 2024, Volume: 25, Issue: 5, Pages: e2024GC011443-1-e2024GC011443-29 |
| ISSN: | 1525-2027 |
| DOI: | 10.1029/2024GC011443 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1029/2024GC011443 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1029/2024GC011443 
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| Author Notes: | E. Ranta, S.A. Halldórsson, B.A. Óladóttir, M A. Pfeffer, A. Caracciolo, E. Bali, G.H. Guðfinnsson, M. Kahl and S. Barsotti |
| Summary: | Outgassing of sulfur (as SO2) is one of the principal hazards posed by volcanic eruptions. However, S emission potentials of most volcanoes globally are poorly constrained due to a short observational record and an incomplete understanding of the magmatic processes that influence pre-eruptive S concentrations. Here, we use a compilation of published and new data from melt inclusions (MIs)—which can preserve magmatic S concentrations prior to eruptive degassing—from the Iceland hotspot to evaluate the effects of mantle melting and crustal magmatic processes on the S budgets of Icelandic melts. We use MI data to estimate S emission potentials (ΔSmax, in ppm S) for 73 eruptions from 22 of Iceland's presently active ∼33 volcanic systems. We show that the S systematics of Icelandic melts are strongly regulated by the sulfide solubility limit. Sulfide-saturated conditions during lower-degree mantle melting, prevalent at off-rift zones, likely explains observed decoupling between S and Cl. During magmatic differentiation, a local maximum in modeled sulfide solubility occurs in evolved basalts (4-6 wt.% MgO), coinciding with highest MI S concentrations. Highest ΔSmax values (2,100-2,600 ppm) are found in the Hekla 1913 CE, Eldgjá 939 CE, and Surtsey 1963-1967 CE eruptions in the South Iceland Volcanic Zone. Our results extend the record of volcanic sulfur emissions back in time and can be used to assess volcanic gas hazards at Icelandic volcanoes where no direct measurements are available. Broadly, the results underline the governing role of sulfide saturation during melting and magma differentiation in controlling the eruptible S contents of Icelandic magmas. |
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| Item Description: | Gesehen am 14.11.2024 |
| Physical Description: | Online Resource |
| ISSN: | 1525-2027 |
| DOI: | 10.1029/2024GC011443 |