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Structural flexibility is a decisive factor in FLP dihydrogen cleavage with tetrahedral Lewis acids: a silane case study

Dihydrogen activation is the paradigmatic reaction of frustrated Lewis pairs (FLPs). While trigonal-planar Lewis acids have been well established in this transformation, tetrahedral Lewis acids are surprisingly limited. Indeed, several cases were computed as thermodynamically and kinetically feasibl...

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Hauptverfasser: Thorwart, Thaddäus (VerfasserIn) , Greb, Lutz (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: August 19, 2024
In: Chemistry - a European journal
Year: 2024, Jahrgang: 30, Heft: 46, Pages: 1-5
ISSN:1521-3765
DOI:10.1002/chem.202401912
Online-Zugang:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/chem.202401912
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202401912
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Verfasserangaben:Thaddäus Thorwart and Lutz Greb

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