Zero-field J-spectroscopy of quadrupolar nuclei
Zero- to ultralow-field nuclear magnetic resonance (ZULF NMR) allows molecular structure elucidation via measurement of electron-mediated spin-spin J-couplings. This study examines zero-field J-spectra from molecules with quadrupolar nuclei, exemplified by solutions of various isotopologues of ammon...
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| Hauptverfasser: | , , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
27 May 2024
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| In: |
Nature Communications
Year: 2024, Jahrgang: 15, Pages: 1-10 |
| ISSN: | 2041-1723 |
| DOI: | 10.1038/s41467-024-48390-2 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1038/s41467-024-48390-2 Verlag, kostenfrei, Volltext: https://www.nature.com/articles/s41467-024-48390-2 |
| Verfasserangaben: | Román Picazo-Frutos, Kirill F. Sheberstov, John W. Blanchard, Erik Van Dyke, Moritz Reh, Tobias Sjoelander, Alexander Pines, Dmitry Budker & Danila A. Barskiy |
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| 520 | |a Zero- to ultralow-field nuclear magnetic resonance (ZULF NMR) allows molecular structure elucidation via measurement of electron-mediated spin-spin J-couplings. This study examines zero-field J-spectra from molecules with quadrupolar nuclei, exemplified by solutions of various isotopologues of ammonium cations. The spectra reveal differences between various isotopologues upon extracting precise J-coupling values from pulse-acquire measurements. | ||
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