Insights for the hydrogen-mediated deoxydehydration (DODH) with Cp*ReO3 and alkene extrusion of related Re(V)-diolates [data]
Experimental Data to the manuscript Insights for the Hydrogen-Mediated Deoxydehydration (DODH) with Cp*ReO3 and Alkene Extrusion of Related Re(V)-Diolates: To transform highly oxygenated molecules such as polyols from biomass into value-added chemicals, the deoxygenation via the deoxydehydration (DO...
Gespeichert in:
| Hauptverfasser: | , , , |
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| Dokumenttyp: | Datenbank Forschungsdaten |
| Sprache: | Englisch |
| Veröffentlicht: |
Heidelberg
Universität
2024-12-19
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| DOI: | 10.11588/data/4706QU |
| Schlagworte: | |
| Online-Zugang: | Resolving-System, kostenfrei, Volltext: https://doi.org/10.11588/data/4706QU Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/data/4706QU 
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| Verfasserangaben: | Yannick Stöckl, Frank Rominger, A. Stephen K. Hashmi, Thomas Schaub |
MARC
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| 245 | 1 | 0 | |a Insights for the hydrogen-mediated deoxydehydration (DODH) with Cp*ReO3 and alkene extrusion of related Re(V)-diolates [data] |c Yannick Stöckl, Frank Rominger, A. Stephen K. Hashmi, Thomas Schaub |
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| 520 | |a Experimental Data to the manuscript Insights for the Hydrogen-Mediated Deoxydehydration (DODH) with Cp*ReO3 and Alkene Extrusion of Related Re(V)-Diolates: To transform highly oxygenated molecules such as polyols from biomass into value-added chemicals, the deoxygenation via the deoxydehydration (DODH) is a promising approach. We report the catalytic DODH of substrates from renewable resources using Cp*ReO3 (1 mol%, TON up to 32) as a catalyst and hydrogen as a reductant. Additionally, the synthesis of Re(V)-diolates is described for tartrates, glycerol and erythritol derivatives. These Re(V)-diolates were obtained in 35 – 53% yield and as mixtures of diastereomers. Their characterization was accomplished using 2D NMR, MS, IR and X-ray diffraction. A NOESY study revealed an intermolecular exchange of glycerol moieties for the diolate complex. Further, alkene extrusion experiments allowed us to establish a reactivity order for a variety of substituents. The olefin extrusion was the fastest for tartrate units and the slowest for glycerol and erythritol diolates. (2024-03-12) | ||
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