Single chamber Mg/Ca analyses of Globigerinoides ruber for paleo-proxy calibration using femtosecond LA-ICP-MS
Mg/Ca is an independent proxy in paleoceanography to reconstruct past seawater temperature. Femtosecond Laser Ablation Inductively Coupled Plasma Mass Spectrometry (fs-LA-ICP-MS) was employed to determine the Mg/Ca composition of tests (shells) of the planktic foraminifer species Globigerinoides rub...
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| Hauptverfasser: | , , , , , , , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
04 June 2024
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| In: |
Scientific data
Year: 2024, Jahrgang: 11, Pages: 1-9 |
| ISSN: | 2052-4463 |
| DOI: | 10.1038/s41597-024-03402-0 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1038/s41597-024-03402-0 Verlag, kostenfrei, Volltext: https://www.nature.com/articles/s41597-024-03402-0 
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| Verfasserangaben: | Alexa Fischer, Ralf Schiebel, Klaus Peter Jochum, Lena Heins, Anthea I. Arns, Hedy M. Aardema, Hans Slagter, Maria Ll Calleja, Noy Levy, Brigitte Stoll, David Walter, Ulrike Weis, Janne Repschläger & Gerald H. Haug |
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| 245 | 1 | 0 | |a Single chamber Mg/Ca analyses of Globigerinoides ruber for paleo-proxy calibration using femtosecond LA-ICP-MS |c Alexa Fischer, Ralf Schiebel, Klaus Peter Jochum, Lena Heins, Anthea I. Arns, Hedy M. Aardema, Hans Slagter, Maria Ll Calleja, Noy Levy, Brigitte Stoll, David Walter, Ulrike Weis, Janne Repschläger & Gerald H. Haug |
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| 520 | |a Mg/Ca is an independent proxy in paleoceanography to reconstruct past seawater temperature. Femtosecond Laser Ablation Inductively Coupled Plasma Mass Spectrometry (fs-LA-ICP-MS) was employed to determine the Mg/Ca composition of tests (shells) of the planktic foraminifer species Globigerinoides ruber albus (white chromotype) and G. ruber ruber (red/pink chromotype) sampled alive from the temperate to subtropical eastern North Atlantic with the research sailing yacht Eugen Seibold. Mg/Ca data are compared to (i) the measured in-situ temperature of ambient seawater, (ii) average mixed layer temperature, and (iii) sea surface temperature (SST). The pooled mean chamber Mg/Ca from each plankton tow site exhibits a positive relationship with SST. Two chamber-specific calibrations are derived, which are consistent with previous calibration equations for comparable paleo-archives. The results confirm fs-LA-ICP-MS as reliable method for determining Mg/Ca in G. ruber, and both the penultimate and antepenultimate chambers of adult specimens may provide comprehensible Mg/Ca temperatures of the surface ocean. | ||
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