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Benzobischalcogeno(3,2-c)quinolines: tuning electronic and structural properties with group 16 elements [data]

Chalcogen-substituted π-extended indolocarbazoles were synthesized through a nucleophilic cyclization of tethered diynes with sulfur, selenium or tellurium sources, followed by a Pictet-Spengler reaction. These combined synthetic strategies enabled the facile access to heptacyclic π-extended molecul...

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Main Authors: Rudolph, Matthias (Author) , Hüßler, Christopher (Author) , Dietl, Martin C. (Author) , Scherr, Matthias (Author) , Butigan, Emma (Author) , Heckershoff, Robin (Author) , Lopes, Eric F. (Author) , Kahle, Justin (Author) , Krämer, Petra (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format: Database Research Data
Language:English
Published: Heidelberg Universität 2025-02-14
DOI:10.11588/DATA/QJXJQL
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Forschungsdaten
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Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.11588/DATA/QJXJQL
Verlag, kostenfrei, Volltext: https://heidata.uni-heidelberg.de/dataset.xhtml?persistentId=doi:10.11588/DATA/QJXJQL
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Author Notes:Matthias Rudolph, Christopher Hüßler, Martin C. Dietl, Matthias Scherr, Emma Butigan, Robin Heckershoff, Eric F. Lopes, Justin Kahle, Petra Krämer, Frank Rominger, A. Stephen K. Hashmi
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Summary:Chalcogen-substituted π-extended indolocarbazoles were synthesized through a nucleophilic cyclization of tethered diynes with sulfur, selenium or tellurium sources, followed by a Pictet-Spengler reaction. These combined synthetic strategies enabled the facile access to heptacyclic π-extended molecules, offering a broad modularity at various stages of the synthesis route. In total, twenty-six novel heptacyclic compounds were synthesized. Their photophysical and structural properties were investigated experimentally as well as theoretically.
Item Description:Im Titel steht 3,2-c in eckiger Klammer
Gefördert durch: Deutsche Forschungsgemeinschaft (DFG): SFB 1249; Hector Fellow Academy: D.120100/20.002; bwHPC: INST 40/575-1 FUGG (JUSTUS 2 cluster)
Gesehen am 17.02.2025
Physical Description:Online Resource
DOI:10.11588/DATA/QJXJQL

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