Synthesis and Characterization of a Copper Dinitrogen Complex Supported by a Weakly Coordinating Anion
We report the synthesis and full characterization of the copper dinitrogen complex [(η1-N2)CuAl(ORF)4] 2 (RF=C(CF3)3) prepared by a cascade metathesis reaction of Ag[Al(ORF)4] with CuI-excess in iso-perfluorohexane (i-pfh) under N2 atmosphere. Title compound 2 features an extraordinarily high N2 str...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
Sep 2024
|
| In: |
Angewandte Chemie. International edition
Year: 2024, Volume: 63, Issue: 38, Pages: 1-7 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.202405330 |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/anie.202405330 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202405330 
|
| Author Notes: | Julie Willrett, Manuel Schmitt, Vadim Zhuravlev, Malte Sellin, Przemysław J. Malinowski, Ingo Krossing |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1917882688 | ||
| 003 | DE-627 | ||
| 005 | 20250716233347.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 250224s2024 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/anie.202405330 |2 doi | |
| 035 | |a (DE-627)1917882688 | ||
| 035 | |a (DE-599)KXP1917882688 | ||
| 035 | |a (OCoLC)1528019594 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Willrett, Julie |e VerfasserIn |0 (DE-588)1357423306 |0 (DE-627)1917893264 |4 aut | |
| 245 | 1 | 0 | |a Synthesis and Characterization of a Copper Dinitrogen Complex Supported by a Weakly Coordinating Anion |c Julie Willrett, Manuel Schmitt, Vadim Zhuravlev, Malte Sellin, Przemysław J. Malinowski, Ingo Krossing |
| 264 | 1 | |c Sep 2024 | |
| 300 | |b Illustrationen | ||
| 300 | |a 7 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Online verfügbar: 10. Juni 2024, Artikelversion: 14. August 2024 | ||
| 500 | |a Gesehen am 24.02.2025 | ||
| 520 | |a We report the synthesis and full characterization of the copper dinitrogen complex [(η1-N2)CuAl(ORF)4] 2 (RF=C(CF3)3) prepared by a cascade metathesis reaction of Ag[Al(ORF)4] with CuI-excess in iso-perfluorohexane (i-pfh) under N2 atmosphere. Title compound 2 features an extraordinarily high N2 stretching frequency at 2313/2314 cm−1 (IR/Raman) and was characterized by single-crystal and powder X-ray diffractometry. Quantum chemical charge displacement analysis based on natural orbitals of chemical valence (CD-NOCV) indicates that the copper-dinitrogen interaction is still governed by weak π-backdonation, but is significantly reduced compared to all literature-known transition metal dinitrogen complexes. | ||
| 650 | 4 | |a copper | |
| 650 | 4 | |a dinitrogen complex | |
| 650 | 4 | |a metathesis | |
| 650 | 4 | |a quantum chemical calculations | |
| 650 | 4 | |a weakly coordinating anion | |
| 700 | 1 | |a Schmitt, Manuel |d 1994- |e VerfasserIn |0 (DE-588)1208032933 |0 (DE-627)1694341801 |4 aut | |
| 700 | 1 | |a Zhuravlev, Vadim |e VerfasserIn |4 aut | |
| 700 | 1 | |a Sellin, Malte |d 1998- |e VerfasserIn |0 (DE-588)1327088746 |0 (DE-627)1886593302 |4 aut | |
| 700 | 1 | |a Malinowski, Przemysław J. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Krossing, Ingo |d 1968- |e VerfasserIn |0 (DE-588)11808125X |0 (DE-627)079232132 |0 (DE-576)291704964 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Angewandte Chemie. International edition |d Weinheim : Wiley-VCH, 1998 |g 63(2024), 38 vom: Sept., Artikel-ID e202405330, Seite 1-7 |h Online-Ressource |w (DE-627)320497879 |w (DE-600)2011836-3 |w (DE-576)111552060 |x 1521-3773 |7 nnas |a Synthesis and Characterization of a Copper Dinitrogen Complex Supported by a Weakly Coordinating Anion |
| 773 | 1 | 8 | |g volume:63 |g year:2024 |g number:38 |g month:09 |g elocationid:e202405330 |g pages:1-7 |g extent:7 |a Synthesis and Characterization of a Copper Dinitrogen Complex Supported by a Weakly Coordinating Anion |
| 856 | 4 | 0 | |u https://doi.org/10.1002/anie.202405330 |x Verlag |x Resolving-System |z kostenfrei |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202405330 |x Verlag |z kostenfrei |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20250224 | ||
| 993 | |a Article | ||
| 994 | |a 2024 | ||
| 998 | |g 1208032933 |a Schmitt, Manuel |m 1208032933:Schmitt, Manuel |d 120000 |d 120200 |e 120000PS1208032933 |e 120200PS1208032933 |k 0/120000/ |k 1/120000/120200/ |p 2 | ||
| 999 | |a KXP-PPN1917882688 |e 467003409X | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"relHost":[{"disp":"Synthesis and Characterization of a Copper Dinitrogen Complex Supported by a Weakly Coordinating AnionAngewandte Chemie. International edition","note":["Gesehen am 20.12.2022","Fortsetzung der Druck-Ausgabe"],"id":{"eki":["320497879"],"doi":["10.1002/(ISSN)1521-3773"],"zdb":["2011836-3"],"issn":["1521-3773"]},"title":[{"title_sort":"Angewandte Chemie","title":"Angewandte Chemie","subtitle":"a journal of the Gesellschaft Deutscher Chemiker","partname":"International edition"}],"language":["eng"],"origin":[{"publisherPlace":"Weinheim","dateIssuedKey":"1998","dateIssuedDisp":"1998-","publisher":"Wiley-VCH"}],"type":{"media":"Online-Ressource","bibl":"periodical"},"part":{"text":"63(2024), 38 vom: Sept., Artikel-ID e202405330, Seite 1-7","issue":"38","volume":"63","extent":"7","year":"2024","pages":"1-7"},"physDesc":[{"extent":"Online-Ressource"}],"recId":"320497879","corporate":[{"roleDisplay":"Herausgebendes Organ","display":"Gesellschaft Deutscher Chemiker","role":"isb"}],"pubHistory":["37.1998 -"],"titleAlt":[{"title":"Angewandte Chemie / International edition"}]}],"name":{"displayForm":["Julie Willrett, Manuel Schmitt, Vadim Zhuravlev, Malte Sellin, Przemysław J. Malinowski, Ingo Krossing"]},"person":[{"family":"Willrett","roleDisplay":"VerfasserIn","given":"Julie","display":"Willrett, Julie","role":"aut"},{"roleDisplay":"VerfasserIn","family":"Schmitt","given":"Manuel","display":"Schmitt, Manuel","role":"aut"},{"family":"Zhuravlev","roleDisplay":"VerfasserIn","given":"Vadim","role":"aut","display":"Zhuravlev, Vadim"},{"family":"Sellin","roleDisplay":"VerfasserIn","role":"aut","display":"Sellin, Malte","given":"Malte"},{"roleDisplay":"VerfasserIn","family":"Malinowski","role":"aut","display":"Malinowski, Przemysław J.","given":"Przemysław J."},{"family":"Krossing","roleDisplay":"VerfasserIn","given":"Ingo","display":"Krossing, Ingo","role":"aut"}],"physDesc":[{"extent":"7 S.","noteIll":"Illustrationen"}],"language":["eng"],"type":{"bibl":"article-journal","media":"Online-Ressource"},"origin":[{"dateIssuedDisp":"Sep 2024","dateIssuedKey":"2024"}],"note":["Online verfügbar: 10. Juni 2024, Artikelversion: 14. August 2024","Gesehen am 24.02.2025"],"id":{"doi":["10.1002/anie.202405330"],"eki":["1917882688"]},"title":[{"title_sort":"Synthesis and Characterization of a Copper Dinitrogen Complex Supported by a Weakly Coordinating Anion","title":"Synthesis and Characterization of a Copper Dinitrogen Complex Supported by a Weakly Coordinating Anion"}],"recId":"1917882688"} | ||
| SRT | |a WILLRETTJUSYNTHESISA2024 | ||