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One step synthesis of 4,6,8-Trimethoxyazulenes: as building block for 2-functionalized azulenes

Here we present a simple gold-catalyzed one-pot reaction of easily available diarylbutadiynes, with trimethoxybenzene as solvent and reactant to synthesize 4,6,8-trimethoxyazulenes. The methoxy substituents, which render the azulene very electron-rich, enable a change of azulenes typical regioselect...

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Hauptverfasser: Wunsch, Jonas (VerfasserIn) , Sommer, Hendrick M. (VerfasserIn) , Kohl, Senta J. (VerfasserIn) , Maier, Rouven (VerfasserIn) , Rudolph, Matthias (VerfasserIn) , Rominger, Frank (VerfasserIn) , Hashmi, A. Stephen K. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 07 January 2025
In: Chemistry - a European journal
Year: 2025, Jahrgang: 31, Heft: 13, Pages: 1-9
ISSN:1521-3765
DOI:10.1002/chem.202404170
Online-Zugang:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/chem.202404170
Verlag, kostenfrei, Volltext: https://www.webofscience.com/api/gateway?GWVersion=2&SrcAuth=DOISource&SrcApp=WOS&KeyAID=10.1002%2Fchem.202404170&DestApp=DOI&SrcAppSID=EUW1ED0F7Foi9lcejdJw9hzzgfZIn&SrcJTitle=CHEMISTRY-A+EUROPEAN+JOURNAL&DestDOIRegistrantName=Wiley+%28John+Wiley+%26+Sons%29
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Verfasserangaben:Jonas F. Wunsch, Hendrick M. Sommer, Senta J. Kohl, Rouven Maier, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi

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650 4 |a 1,3-DIYNES 
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650 4 |a ELECTROPHILIC SUBSTITUTION 
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