Dehydrogenative coupling reactions with guanidino-functionalized aromatics
Dehydrogenative coupling (DC) reactions are of importance for the construction of new carbon-element bonds in synthetic organic chemistry. In this work, we report on the synthesis and characterization of several redox-active guanidino-functionalized aromatic molecules (GFAs) for use in DC (C−C and C...
Gespeichert in:
| Hauptverfasser: | , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
December 18, 2024
|
| In: |
Chemistry - a European journal
Year: 2024, Jahrgang: 30, Heft: 71, Pages: 1-16 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.202402917 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/chem.202402917 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202402917 
|
| Verfasserangaben: | Petra Walter, Maximilian Schulz, Olaf Hübner, Andrei Poddelskii, Elisabeth Kaifer, and Hans-Jörg Himmel |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1925465969 | ||
| 003 | DE-627 | ||
| 005 | 20250717013433.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 250513s2024 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/chem.202402917 |2 doi | |
| 035 | |a (DE-627)1925465969 | ||
| 035 | |a (DE-599)KXP1925465969 | ||
| 035 | |a (OCoLC)1528045235 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Walter, Petra |d 1964- |e VerfasserIn |0 (DE-588)1160881383 |0 (DE-627)1024274144 |0 (DE-576)506212955 |4 aut | |
| 245 | 1 | 0 | |a Dehydrogenative coupling reactions with guanidino-functionalized aromatics |c Petra Walter, Maximilian Schulz, Olaf Hübner, Andrei Poddelskii, Elisabeth Kaifer, and Hans-Jörg Himmel |
| 264 | 1 | |c December 18, 2024 | |
| 300 | |b Illustrationen | ||
| 300 | |a 16 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Online verfügbar: 07. Oktober 2024 | ||
| 500 | |a Gesehen am 13.05.2025 | ||
| 520 | |a Dehydrogenative coupling (DC) reactions are of importance for the construction of new carbon-element bonds in synthetic organic chemistry. In this work, we report on the synthesis and characterization of several redox-active guanidino-functionalized aromatic molecules (GFAs) for use in DC (C−C and C−O) reactions. In a systematic approach, we first characterize the new DC reagents in all relevant redox and protonation states, and compare their performance in competitive test proton-coupled electron transfer (PCET) reactions. Then, their use in four different DC reactions with different mechanisms is evaluated. | ||
| 650 | 4 | |a dehydrogenative coupling reactions | |
| 650 | 4 | |a guanidines | |
| 650 | 4 | |a oxidative coupling | |
| 650 | 4 | |a proton-coupled electron transfer | |
| 650 | 4 | |a redox-acive molecules | |
| 700 | 1 | |a Schulz, Maximilian |e VerfasserIn |0 (DE-588)1358417156 |0 (DE-627)1918879753 |4 aut | |
| 700 | 1 | |a Hübner, Olaf |e VerfasserIn |0 (DE-588)1020547707 |0 (DE-627)691256500 |0 (DE-576)360702864 |4 aut | |
| 700 | 1 | |a Poddel'sky, Andrey |e VerfasserIn |0 (DE-588)1325784516 |0 (DE-627)188557259X |4 aut | |
| 700 | 1 | |a Kaifer, Elisabeth |e VerfasserIn |0 (DE-588)1020547898 |0 (DE-627)691256624 |0 (DE-576)166913820 |4 aut | |
| 700 | 1 | |a Himmel, Hans-Jörg |d 1970- |e VerfasserIn |0 (DE-588)120090368 |0 (DE-627)080439683 |0 (DE-576)292036159 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Chemistry - a European journal |d Weinheim : Wiley-VCH, 1995 |g 30(2024), 71, Artikel-ID e202402917, Seite 1-16 |h Online-Ressource |w (DE-627)270935193 |w (DE-600)1478547-X |w (DE-576)078707404 |x 1521-3765 |7 nnas |a Dehydrogenative coupling reactions with guanidino-functionalized aromatics |
| 773 | 1 | 8 | |g volume:30 |g year:2024 |g number:71 |g elocationid:e202402917 |g pages:1-16 |g extent:16 |a Dehydrogenative coupling reactions with guanidino-functionalized aromatics |
| 856 | 4 | 0 | |u https://doi.org/10.1002/chem.202402917 |x Verlag |x Resolving-System |z kostenfrei |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202402917 |x Verlag |z kostenfrei |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20250513 | ||
| 993 | |a Article | ||
| 994 | |a 2024 | ||
| 998 | |g 120090368 |a Himmel, Hans-Jörg |m 120090368:Himmel, Hans-Jörg |d 120000 |d 120200 |e 120000PH120090368 |e 120200PH120090368 |k 0/120000/ |k 1/120000/120200/ |p 6 |y j | ||
| 998 | |g 1020547898 |a Kaifer, Elisabeth |m 1020547898:Kaifer, Elisabeth |d 120000 |d 120200 |e 120000PK1020547898 |e 120200PK1020547898 |k 0/120000/ |k 1/120000/120200/ |p 5 | ||
| 998 | |g 1325784516 |a Poddel'sky, Andrey |m 1325784516:Poddel'sky, Andrey |d 120000 |d 120200 |e 120000PP1325784516 |e 120200PP1325784516 |k 0/120000/ |k 1/120000/120200/ |p 4 | ||
| 998 | |g 1020547707 |a Hübner, Olaf |m 1020547707:Hübner, Olaf |d 500000 |d 501249 |e 500000PH1020547707 |e 501249PH1020547707 |k 0/500000/ |k 1/500000/501249/ |p 3 | ||
| 998 | |g 1358417156 |a Schulz, Maximilian |m 1358417156:Schulz, Maximilian |d 120000 |d 120200 |e 120000PS1358417156 |e 120200PS1358417156 |k 0/120000/ |k 1/120000/120200/ |p 2 | ||
| 998 | |g 1160881383 |a Walter, Petra |m 1160881383:Walter, Petra |d 120000 |d 120200 |e 120000PW1160881383 |e 120200PW1160881383 |k 0/120000/ |k 1/120000/120200/ |p 1 |x j | ||
| 999 | |a KXP-PPN1925465969 |e 472383057X | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"id":{"doi":["10.1002/chem.202402917"],"eki":["1925465969"]},"name":{"displayForm":["Petra Walter, Maximilian Schulz, Olaf Hübner, Andrei Poddelskii, Elisabeth Kaifer, and Hans-Jörg Himmel"]},"physDesc":[{"noteIll":"Illustrationen","extent":"16 S."}],"recId":"1925465969","relHost":[{"origin":[{"publisher":"Wiley-VCH","dateIssuedKey":"1995","dateIssuedDisp":"1995-","publisherPlace":"Weinheim"}],"pubHistory":["1.1995 -"],"note":["Fortsetzung der Druck-Ausgabe","Gesehen am 27. Februar 2017"],"title":[{"title":"Chemistry - a European journal","title_sort":"Chemistry - a European journal"}],"disp":"Dehydrogenative coupling reactions with guanidino-functionalized aromaticsChemistry - a European journal","type":{"bibl":"periodical","media":"Online-Ressource"},"recId":"270935193","physDesc":[{"extent":"Online-Ressource"}],"id":{"eki":["270935193"],"zdb":["1478547-X"],"issn":["1521-3765"],"doi":["10.1002/(ISSN)1521-3765"]},"language":["eng"],"part":{"volume":"30","extent":"16","pages":"1-16","year":"2024","text":"30(2024), 71, Artikel-ID e202402917, Seite 1-16","issue":"71"}}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"origin":[{"dateIssuedDisp":"December 18, 2024","dateIssuedKey":"2024"}],"note":["Online verfügbar: 07. Oktober 2024","Gesehen am 13.05.2025"],"title":[{"title":"Dehydrogenative coupling reactions with guanidino-functionalized aromatics","title_sort":"Dehydrogenative coupling reactions with guanidino-functionalized aromatics"}],"language":["eng"],"person":[{"display":"Walter, Petra","family":"Walter","given":"Petra","role":"aut"},{"given":"Maximilian","role":"aut","display":"Schulz, Maximilian","family":"Schulz"},{"given":"Olaf","role":"aut","family":"Hübner","display":"Hübner, Olaf"},{"role":"aut","given":"Andrey","display":"Poddel'sky, Andrey","family":"Poddel'sky"},{"role":"aut","given":"Elisabeth","family":"Kaifer","display":"Kaifer, Elisabeth"},{"role":"aut","given":"Hans-Jörg","family":"Himmel","display":"Himmel, Hans-Jörg"}]} | ||
| SRT | |a WALTERPETRDEHYDROGEN1820 | ||