Structural constraint at a P-P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism
Structurally constraining p-block elements has become a powerful strategy for bond activation chemistry with main group compounds. Traditionally, this approach focuses on mononuclear centers, yet applying structural constraints to systems with element-element bonds remains underexplored. In this stu...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
2025
|
| In: |
Chemical science
Year: 2025, Volume: 16, Issue: 4, Pages: 1716-1721 |
| ISSN: | 2041-6539 |
| DOI: | 10.1039/D4SC06581F |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D4SC06581F Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2025/sc/d4sc06581f 
|
| Author Notes: | Lijun You, Daniel Roth and Lutz Greb |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1925730026 | ||
| 003 | DE-627 | ||
| 005 | 20250717014013.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 250515s2025 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1039/D4SC06581F |2 doi | |
| 035 | |a (DE-627)1925730026 | ||
| 035 | |a (DE-599)KXP1925730026 | ||
| 035 | |a (OCoLC)1528045371 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a You, Lijun |e VerfasserIn |0 (DE-588)1365689980 |0 (DE-627)1925730840 |4 aut | |
| 245 | 1 | 0 | |a Structural constraint at a P-P bond |b phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism |c Lijun You, Daniel Roth and Lutz Greb |
| 264 | 1 | |c 2025 | |
| 300 | |b Illustrationen | ||
| 300 | |a 5 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 15.05.2025 | ||
| 520 | |a Structurally constraining p-block elements has become a powerful strategy for bond activation chemistry with main group compounds. Traditionally, this approach focuses on mononuclear centers, yet applying structural constraints to systems with element-element bonds remains underexplored. In this study, we introduce a cation featuring a structural constraint-elongated P-P bond that spontaneously adds to unactivated alkynes, alkenes, aldehydes, and ketones. Despite its positive charge, the surprisingly apolar P-P+ bond promotes phosphinophosphination via a concerted, highly regio- and diastereoselective mechanism. This unique reactivity opens pathways to novel seven-membered phosphorus heterocycles with customizable optical properties and a structurally varied array of ligands for transition metal coordination. | ||
| 700 | 1 | |a Roth, Daniel |d 1997- |e VerfasserIn |0 (DE-588)1244322954 |0 (DE-627)1775580180 |4 aut | |
| 700 | 1 | |a Greb, Lutz |e VerfasserIn |0 (DE-588)1043619879 |0 (DE-627)770726526 |0 (DE-576)395158265 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Chemical science |d Cambridge : RSC, 2010 |g 16(2025), 4, Seite 1716-1721 |h Online-Ressource |w (DE-627)629702934 |w (DE-600)2559110-1 |w (DE-576)325003831 |x 2041-6539 |7 nnas |a Structural constraint at a P-P bond phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism |
| 773 | 1 | 8 | |g volume:16 |g year:2025 |g number:4 |g pages:1716-1721 |g extent:5 |a Structural constraint at a P-P bond phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism |
| 856 | 4 | 0 | |u https://doi.org/10.1039/D4SC06581F |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://pubs.rsc.org/en/content/articlelanding/2025/sc/d4sc06581f |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20250515 | ||
| 993 | |a Article | ||
| 994 | |a 2025 | ||
| 998 | |g 1043619879 |a Greb, Lutz |m 1043619879:Greb, Lutz |d 120000 |d 120200 |e 120000PG1043619879 |e 120200PG1043619879 |k 0/120000/ |k 1/120000/120200/ |p 3 |y j | ||
| 998 | |g 1244322954 |a Roth, Daniel |m 1244322954:Roth, Daniel |p 2 | ||
| 998 | |g 1365689980 |a You, Lijun |m 1365689980:You, Lijun |d 120000 |e 120000PY1365689980 |k 0/120000/ |p 1 |x j | ||
| 999 | |a KXP-PPN1925730026 |e 4724698241 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"title":[{"title_sort":"Structural constraint at a P-P bond","title":"Structural constraint at a P-P bond","subtitle":"phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism"}],"name":{"displayForm":["Lijun You, Daniel Roth and Lutz Greb"]},"type":{"bibl":"article-journal","media":"Online-Ressource"},"id":{"doi":["10.1039/D4SC06581F"],"eki":["1925730026"]},"person":[{"display":"You, Lijun","role":"aut","family":"You","given":"Lijun"},{"given":"Daniel","display":"Roth, Daniel","role":"aut","family":"Roth"},{"given":"Lutz","role":"aut","display":"Greb, Lutz","family":"Greb"}],"origin":[{"dateIssuedKey":"2025","dateIssuedDisp":"2025"}],"language":["eng"],"note":["Gesehen am 15.05.2025"],"physDesc":[{"noteIll":"Illustrationen","extent":"5 S."}],"recId":"1925730026","relHost":[{"name":{"displayForm":["RSC, Royal Society of Chemistry"]},"disp":"Structural constraint at a P-P bond phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanismChemical science","title":[{"title_sort":"Chemical science","title":"Chemical science"}],"origin":[{"dateIssuedDisp":"2010-","publisherPlace":"Cambridge","dateIssuedKey":"2010","publisher":"RSC"}],"part":{"extent":"5","volume":"16","issue":"4","pages":"1716-1721","year":"2025","text":"16(2025), 4, Seite 1716-1721"},"id":{"eki":["629702934"],"issn":["2041-6539"],"zdb":["2559110-1"]},"language":["eng"],"pubHistory":["1.2010 -"],"type":{"media":"Online-Ressource","bibl":"periodical"},"note":["Gesehen am 04.11.25"],"corporate":[{"role":"isb","display":"Royal Society of Chemistry"}],"physDesc":[{"extent":"Online-Ressource"}],"recId":"629702934"}]} | ||
| SRT | |a YOULIJUNROSTRUCTURAL2025 | ||