The synthesis and structural aspects of the perbromo-functionalised thiaboranes closo-SBnBrn (n = 5, 9, 11): the solid-state structure of the octahedral closo-SB5Br5, governed by strong dihalogen contacts
Co-pyrolysis reactions of B2Br4 with S2Br2 at 350 °C in vacuo yielded the brominated thiaboranes closo-SB5Br5 (1), closo-1-SB9Br9 (2) and closo-SB11Br11 (3), confirmed by high-resolution mass spectrometry, experimental and computational 11B NMR spectroscopy. The strong Brδ+(σ-hole)⋯Brδ−(ring) attrac...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
4 February 2025
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| In: |
Chemical communications
Year: 2025, Jahrgang: 61, Heft: 12, Pages: 2528-2531 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/D4CC06334A |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D4CC06334A Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2025/cc/d4cc06334a 
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| Verfasserangaben: | Willi Keller, Joachim Ballmann, Jindřich Fanfrlík and Drahomír Hnyk |
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| 245 | 1 | 4 | |a The synthesis and structural aspects of the perbromo-functionalised thiaboranes closo-SBnBrn (n = 5, 9, 11) |b the solid-state structure of the octahedral closo-SB5Br5, governed by strong dihalogen contacts |c Willi Keller, Joachim Ballmann, Jindřich Fanfrlík and Drahomír Hnyk |
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| 246 | 3 | 3 | |a The synthesis and structural aspects of the perbromo-functionalised thiaboranes closo-SB n Br n (n = 5, 9, 11) |
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| 520 | |a Co-pyrolysis reactions of B2Br4 with S2Br2 at 350 °C in vacuo yielded the brominated thiaboranes closo-SB5Br5 (1), closo-1-SB9Br9 (2) and closo-SB11Br11 (3), confirmed by high-resolution mass spectrometry, experimental and computational 11B NMR spectroscopy. The strong Brδ+(σ-hole)⋯Brδ−(ring) attraction has been the decisive energy contribution in the crystal of 1. | ||
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