Supramolecular complexation of C60 and C70 by helical nanographene incorporating N-heterotriangulene and hexabenzocoronene subunits
Supramolecular host-guest complexes are studied in the gas-phase evaluating a new host molecule for fullerenes (C60 and C70). The new host molecule is a double N-heterotriangulene-[5]helicene (NTH), consisting of two N-heterotriangulene (N-HTA) blades embedded into a hexabenzocoronene-like backbone...
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| Hauptverfasser: | , , , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
[31 Jan 2025]
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| In: |
RSC Advances
Year: 2025, Jahrgang: 15, Heft: 5, Pages: 3250-3258 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/D4RA07837C |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1039/D4RA07837C Verlag, kostenfrei, Volltext: https://pubs.rsc.org/en/content/articlelanding/2025/ra/d4ra07837c 
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| Verfasserangaben: | Marina Kinzelmann, Nina Fröhlich, Frederik Gnannt, Jan Borstelmann, Stefan Frühwald, Christoph Oleszak, Norbert Jux, Andreas Görling, Milan Kivala and Thomas Drewello |
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| 245 | 1 | 0 | |a Supramolecular complexation of C60 and C70 by helical nanographene incorporating N-heterotriangulene and hexabenzocoronene subunits |c Marina Kinzelmann, Nina Fröhlich, Frederik Gnannt, Jan Borstelmann, Stefan Frühwald, Christoph Oleszak, Norbert Jux, Andreas Görling, Milan Kivala and Thomas Drewello |
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| 520 | |a Supramolecular host-guest complexes are studied in the gas-phase evaluating a new host molecule for fullerenes (C60 and C70). The new host molecule is a double N-heterotriangulene-[5]helicene (NTH), consisting of two N-heterotriangulene (N-HTA) blades embedded into a hexabenzocoronene-like backbone with helically curved topology. Host-guest complexes of [1:1]+˙/2+, [1:2]+˙/2+, [2:1]2+ and [2:3]2+ stoichiometry and charge state are formed by electrospray ionization-mass spectrometry (ESI-MS). Ion formation occurs through electrochemical oxidation of the N-HTA moieties. Energy-resolved collision-induced dissociation (ER-CID) experiments reveal the noncovalent binding of the fullerenes to the NTH molecule and provide an order of stability for the complexes. Density-functional theory (DFT) calculations establish the lowest energy geometries of the complexes. | ||
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