Copper(III) organometallic complexes of non (anti)aromatic and aromatic doubly N-confused porphyrinoids: syntheses and characterization
The retrosynthetic design and synthesis of three unprecedented doubly N-confused porphyrinoids with tunable aromaticity are reported. The controlled modification of the type of oxidant (chloranil vs. DDQ) led to the isolation of cross-conjugated doubly N-confused porphyrinoid 7 (upon chloranil oxida...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
27 Jan 2025
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| In: |
Dalton transactions
Year: 2025, Jahrgang: 54, Heft: 10, Pages: 4267-4275 |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/D4DT03265A |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D4DT03265A Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2025/dt/d4dt03265a 
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| Verfasserangaben: | Anirban Panua, Gunasekaran Velmurugan, Peter Comba and Harapriya Rath |
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| 245 | 1 | 0 | |a Copper(III) organometallic complexes of non (anti)aromatic and aromatic doubly N-confused porphyrinoids |b syntheses and characterization |c Anirban Panua, Gunasekaran Velmurugan, Peter Comba and Harapriya Rath |
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| 520 | |a The retrosynthetic design and synthesis of three unprecedented doubly N-confused porphyrinoids with tunable aromaticity are reported. The controlled modification of the type of oxidant (chloranil vs. DDQ) led to the isolation of cross-conjugated doubly N-confused porphyrinoid 7 (upon chloranil oxidation) and Hϋckel aromatic porphyrinoid 8, while DDQ oxidation led to the [16]π Hϋckel-antiaromatic porphyrinoid 9. All three hybrid N-confused porphyrinoids 7-9 have been thoroughly characterized via solution-state spectroscopic measurements and in-depth DFT studies. While 7 and 8 could form respective Cu(III) organometallic complexes, porphyrinoid 9 remained unsusceptible to Cu metallation. | ||
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