Interlaboratory study on Sb2S3 interplay between structure, dielectric function, and amorphous-to-crystalline phase change for photonics
Antimony sulfide, Sb2S3, is interesting as the phase-change material for applications requiring high transmission from the visible to telecom wavelengths, with its band gap tunable from 2.2 to 1.6 eV, depending on the amorphous and crystalline phase. Here we present results from an interlaboratory s...
Saved in:
| Main Authors: | , , , , , , , , , , , , , , , , , , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
17 June 2022
|
| In: |
iScience
Year: 2022, Volume: 25, Issue: 6, Pages: 1-26 |
| ISSN: | 2589-0042 |
| DOI: | 10.1016/j.isci.2022.104377 |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1016/j.isci.2022.104377 Verlag, kostenfrei, Volltext: https://www.sciencedirect.com/science/article/pii/S2589004222006484 
|
| Author Notes: | Yael Gutiérrez, Anna P. Ovvyan, Gonzalo Santos, Dilson Juan, Saul A. Rosales, Javier Junquera, Pablo García-Fernández, Stefano Dicorato, Maria M. Giangregorio, Elena Dilonardo, Fabio Palumbo, Mircea Modreanu, Josef Resl, Olga Ishchenko, Guy Garry, Tigers Jonuzi, Marin Georghe, Cornel Cobianu, Kurt Hingerl, Christoph Cobet, Fernando Moreno, Wolfram H. P. Pernice, Maria Losurdo |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1933093595 | ||
| 003 | DE-627 | ||
| 005 | 20250913141824.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 250813s2022 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.isci.2022.104377 |2 doi | |
| 035 | |a (DE-627)1933093595 | ||
| 035 | |a (DE-599)KXP1933093595 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Gutiérrez, Yael |e VerfasserIn |0 (DE-588)1373717815 |0 (DE-627)1933092572 |4 aut | |
| 245 | 1 | 0 | |a Interlaboratory study on Sb2S3 interplay between structure, dielectric function, and amorphous-to-crystalline phase change for photonics |c Yael Gutiérrez, Anna P. Ovvyan, Gonzalo Santos, Dilson Juan, Saul A. Rosales, Javier Junquera, Pablo García-Fernández, Stefano Dicorato, Maria M. Giangregorio, Elena Dilonardo, Fabio Palumbo, Mircea Modreanu, Josef Resl, Olga Ishchenko, Guy Garry, Tigers Jonuzi, Marin Georghe, Cornel Cobianu, Kurt Hingerl, Christoph Cobet, Fernando Moreno, Wolfram H. P. Pernice, Maria Losurdo |
| 246 | 3 | 3 | |a Interlaboratory study on Sb 2 S 3 interplay between structure, dielectric function, and amorphous-to-crystalline phase change for photonics |
| 264 | 1 | |c 17 June 2022 | |
| 300 | |b Illustrationen | ||
| 300 | |a 26 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Die Zahlen 2 und 3 im Titel sind hochgestellt | ||
| 500 | |a Gesehen am 13.08.2025 | ||
| 520 | |a Antimony sulfide, Sb2S3, is interesting as the phase-change material for applications requiring high transmission from the visible to telecom wavelengths, with its band gap tunable from 2.2 to 1.6 eV, depending on the amorphous and crystalline phase. Here we present results from an interlaboratory study on the interplay between the structural change and resulting optical contrast during the amorphous-to-crystalline transformation triggered both thermally and optically. By statistical analysis of Raman and ellipsometric spectroscopic data, we have identified two regimes of crystallization, namely 250°C ≤ T < 300°C, resulting in Type-I spherulitic crystallization yielding an optical contrast Δn ∼ 0.4, and 300 ≤ T < 350°C, yielding Type-II crystallization bended spherulitic structure with different dielectric function and optical contrast Δn ∼ 0.2 below 1.5 eV. Based on our findings, applications of on-chip reconfigurable nanophotonic phase modulators and of a reconfigurable high-refractive-index core/phase-change shell nanoantenna are designed and proposed. | ||
| 650 | 4 | |a Applied sciences | |
| 650 | 4 | |a Materials science | |
| 650 | 4 | |a Photonics | |
| 700 | 1 | |a Ovvyan, Anna P. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Santos, Gonzalo |e VerfasserIn |4 aut | |
| 700 | 1 | |a Juan, Dilson |e VerfasserIn |4 aut | |
| 700 | 1 | |a Rosales, Saul A. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Junquera, Javier |e VerfasserIn |4 aut | |
| 700 | 1 | |a García-Fernández, Pablo |e VerfasserIn |4 aut | |
| 700 | 1 | |a Dicorato, Stefano |e VerfasserIn |4 aut | |
| 700 | 1 | |a Giangregorio, Maria M. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Dilonardo, Elena |e VerfasserIn |4 aut | |
| 700 | 1 | |a Palumbo, Fabio |e VerfasserIn |4 aut | |
| 700 | 1 | |a Modreanu, Mircea |e VerfasserIn |4 aut | |
| 700 | 1 | |a Resl, Josef |e VerfasserIn |4 aut | |
| 700 | 1 | |a Ishchenko, Olga |e VerfasserIn |4 aut | |
| 700 | 1 | |a Garry, Guy |e VerfasserIn |4 aut | |
| 700 | 1 | |a Jonuzi, Tigers |e VerfasserIn |4 aut | |
| 700 | 1 | |a Georghe, Marin |e VerfasserIn |4 aut | |
| 700 | 1 | |a Cobianu, Cornel |e VerfasserIn |4 aut | |
| 700 | 1 | |a Hingerl, Kurt |e VerfasserIn |4 aut | |
| 700 | 1 | |a Cobet, Christoph |e VerfasserIn |4 aut | |
| 700 | 1 | |a Moreno, Fernando |e VerfasserIn |4 aut | |
| 700 | 1 | |a Pernice, Wolfram |e VerfasserIn |0 (DE-588)103448429X |0 (DE-627)745631037 |0 (DE-576)382086015 |4 aut | |
| 700 | 1 | |a Losurdo, Maria |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t iScience |d Amsterdam : Elsevier, 2018 |g 25(2022), 6 vom: Juni, Artikel-ID 104377, Seite 1-26 |h Online-Ressource |w (DE-627)1019532106 |w (DE-600)2927064-9 |w (DE-576)502115858 |x 2589-0042 |7 nnas |a Interlaboratory study on Sb2S3 interplay between structure, dielectric function, and amorphous-to-crystalline phase change for photonics |
| 773 | 1 | 8 | |g volume:25 |g year:2022 |g number:6 |g month:06 |g elocationid:104377 |g pages:1-26 |g extent:26 |a Interlaboratory study on Sb2S3 interplay between structure, dielectric function, and amorphous-to-crystalline phase change for photonics |
| 787 | 0 | 8 | |i Errata |a Gutiérrez, Yael |t Correction: Interlaboratory study on Sb2S3 interplay between structure, dielectric function, and amorphous-to-crystalline phase change for photonics |d 2024 |w (DE-627)1933091665 |
| 856 | 4 | 0 | |u https://doi.org/10.1016/j.isci.2022.104377 |x Verlag |x Resolving-System |z kostenfrei |3 Volltext |
| 856 | 4 | 0 | |u https://www.sciencedirect.com/science/article/pii/S2589004222006484 |x Verlag |z kostenfrei |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20250813 | ||
| 993 | |a Article | ||
| 994 | |a 2022 | ||
| 998 | |g 103448429X |a Pernice, Wolfram |m 103448429X:Pernice, Wolfram |d 130000 |d 130700 |e 130000PP103448429X |e 130700PP103448429X |k 0/130000/ |k 1/130000/130700/ |p 22 | ||
| 999 | |a KXP-PPN1933093595 |e 4756905161 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"origin":[{"dateIssuedKey":"2022","dateIssuedDisp":"17 June 2022"}],"language":["eng"],"physDesc":[{"noteIll":"Illustrationen","extent":"26 S."}],"relHost":[{"title":[{"title_sort":"iScience","title":"iScience"}],"language":["eng"],"disp":"Interlaboratory study on Sb2S3 interplay between structure, dielectric function, and amorphous-to-crystalline phase change for photonicsiScience","part":{"volume":"25","text":"25(2022), 6 vom: Juni, Artikel-ID 104377, Seite 1-26","extent":"26","year":"2022","pages":"1-26","issue":"6"},"physDesc":[{"extent":"Online-Ressource"}],"note":["Gesehen am 11.09.2018"],"type":{"bibl":"periodical","media":"Online-Ressource"},"pubHistory":["Volume 1 (March 23, 2018)-"],"origin":[{"dateIssuedDisp":"[2018]-","publisherPlace":"Amsterdam ; Boston ; London ; New York ; Oxford ; Paris ; Philadelphia ; San Diego ; St. Louis","publisher":"Elsevier"}],"recId":"1019532106","id":{"issn":["2589-0042"],"zdb":["2927064-9"],"eki":["1019532106"]}}],"note":["Die Zahlen 2 und 3 im Titel sind hochgestellt","Gesehen am 13.08.2025"],"name":{"displayForm":["Yael Gutiérrez, Anna P. Ovvyan, Gonzalo Santos, Dilson Juan, Saul A. Rosales, Javier Junquera, Pablo García-Fernández, Stefano Dicorato, Maria M. Giangregorio, Elena Dilonardo, Fabio Palumbo, Mircea Modreanu, Josef Resl, Olga Ishchenko, Guy Garry, Tigers Jonuzi, Marin Georghe, Cornel Cobianu, Kurt Hingerl, Christoph Cobet, Fernando Moreno, Wolfram H. P. Pernice, Maria Losurdo"]},"recId":"1933093595","id":{"doi":["10.1016/j.isci.2022.104377"],"eki":["1933093595"]},"title":[{"title":"Interlaboratory study on Sb2S3 interplay between structure, dielectric function, and amorphous-to-crystalline phase change for photonics","title_sort":"Interlaboratory study on Sb2S3 interplay between structure, dielectric function, and amorphous-to-crystalline phase change for photonics"}],"titleAlt":[{"title":"Interlaboratory study on Sb 2 S 3 interplay between structure, dielectric function, and amorphous-to-crystalline phase change for photonics"}],"person":[{"family":"Gutiérrez","roleDisplay":"VerfasserIn","display":"Gutiérrez, Yael","given":"Yael","role":"aut"},{"family":"Ovvyan","display":"Ovvyan, Anna P.","roleDisplay":"VerfasserIn","given":"Anna P.","role":"aut"},{"role":"aut","roleDisplay":"VerfasserIn","display":"Santos, Gonzalo","given":"Gonzalo","family":"Santos"},{"display":"Juan, Dilson","roleDisplay":"VerfasserIn","given":"Dilson","family":"Juan","role":"aut"},{"display":"Rosales, Saul A.","roleDisplay":"VerfasserIn","given":"Saul A.","family":"Rosales","role":"aut"},{"given":"Javier","roleDisplay":"VerfasserIn","display":"Junquera, Javier","family":"Junquera","role":"aut"},{"family":"García-Fernández","display":"García-Fernández, Pablo","roleDisplay":"VerfasserIn","given":"Pablo","role":"aut"},{"display":"Dicorato, Stefano","roleDisplay":"VerfasserIn","given":"Stefano","family":"Dicorato","role":"aut"},{"role":"aut","given":"Maria M.","roleDisplay":"VerfasserIn","display":"Giangregorio, Maria M.","family":"Giangregorio"},{"role":"aut","family":"Dilonardo","roleDisplay":"VerfasserIn","display":"Dilonardo, Elena","given":"Elena"},{"role":"aut","given":"Fabio","roleDisplay":"VerfasserIn","display":"Palumbo, Fabio","family":"Palumbo"},{"role":"aut","display":"Modreanu, Mircea","roleDisplay":"VerfasserIn","given":"Mircea","family":"Modreanu"},{"role":"aut","family":"Resl","given":"Josef","roleDisplay":"VerfasserIn","display":"Resl, Josef"},{"family":"Ishchenko","display":"Ishchenko, Olga","roleDisplay":"VerfasserIn","given":"Olga","role":"aut"},{"role":"aut","display":"Garry, Guy","roleDisplay":"VerfasserIn","given":"Guy","family":"Garry"},{"family":"Jonuzi","display":"Jonuzi, Tigers","roleDisplay":"VerfasserIn","given":"Tigers","role":"aut"},{"role":"aut","family":"Georghe","display":"Georghe, Marin","roleDisplay":"VerfasserIn","given":"Marin"},{"role":"aut","roleDisplay":"VerfasserIn","given":"Cornel","display":"Cobianu, Cornel","family":"Cobianu"},{"role":"aut","given":"Kurt","roleDisplay":"VerfasserIn","display":"Hingerl, Kurt","family":"Hingerl"},{"role":"aut","display":"Cobet, Christoph","roleDisplay":"VerfasserIn","given":"Christoph","family":"Cobet"},{"roleDisplay":"VerfasserIn","given":"Fernando","display":"Moreno, Fernando","family":"Moreno","role":"aut"},{"role":"aut","family":"Pernice","roleDisplay":"VerfasserIn","given":"Wolfram","display":"Pernice, Wolfram"},{"role":"aut","roleDisplay":"VerfasserIn","given":"Maria","display":"Losurdo, Maria","family":"Losurdo"}],"type":{"bibl":"article-journal","media":"Online-Ressource"}} | ||
| SRT | |a GUTIERREZYINTERLABOR1720 | ||